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359556

Sigma-Aldrich

4-Azidoaniline hydrochloride

97%

Sinonimo/i:

4-Aminophenyl azide hydrochloride

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About This Item

Formula condensata:
N3C6H4NH2 · HCl
Numero CAS:
91159-79-4
Peso molecolare:
170.60
Beilstein:
7942921
Numero MDL:
MFCD00043274
Codice UNSPSC:
12352100
ID PubChem:
24862089
NACRES:
NA.22

Livello qualitativo

200

Saggio

97%

Impiego in reazioni chimiche

reaction type: click chemistry

Punto di fusione

165 °C (dec.) (lit.)

Stringa SMILE

Cl.Nc1ccc(cc1)N=[N+]=[N-]

InChI

1S/C6H6N4.ClH/c7-5-1-3-6(4-2-5)9-10-8;/h1-4H,7H2;1H
SDYAJRBHPPWHSF-UHFFFAOYSA-N

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Applicazioni

4-Azidoaniline hydrochloride is suitable for use in the preparation of photo-reactive polymers, poly(acrylic acid) having encorporated phenylazido groups. It may be used in the preparation of 1-(4-aminophenyl)-1H-[1,2,3]-triazol-4-ylcarbonyl-Phe-Gly-Phe-Gly-OH. It is suitable for use in the synthesis of photo-reactive polysaccharides.

Pittogrammi

FlameSkull and crossbones
GHS02,GHS06

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

4.1B - Flammable solid hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
STBH8829
STBG1960V
STBF0875V
STBD9378V
BCBG8985V

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The photochemistry of p-azidoaniline was studied in argon matrices in the absence and presence of oxygen. With the help of quantum chemical calculations we were able to characterize the triplet p-aminophenylnitrene as well as the cis- and trans-p-aminophenylnitroso oxides. It
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