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223441

Sigma-Aldrich

Sodium hydride

greener alternative

dry, 90%

Sinonimo/i:

Sodium monohydride

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About This Item

Formula condensata:
NaH
Numero CAS:
Peso molecolare:
24.00
Numero CE:
Numero MDL:
Codice UNSPSC:
26111700
eCl@ss:
38100205
ID PubChem:
NACRES:
NA.22

Saggio

90%

Stato

powder

Impiego in reazioni chimiche

reagent type: reductant

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Punto di fusione

800 °C (dec.) (lit.)

Categoria alternativa più verde

Stringa SMILE

[Na]

InChI

1S/Na.H
MPMYQQHEHYDOCL-UHFFFAOYSA-N

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Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Applicazioni

Direct intercalation into C60 results in the superconducting material (NaH)4C60.
Sodium hydride (dry) (NaH) can be used for a variety of applications such as:
  • preparation of sodium aluminum hydride (NaAlH4), which can be used as a hydrogen storage material
  • a base and a reducing agent for the deprotonation of alcohols, phenols, amides, ketones, and different functional groups
  • a hydride donor that can be used in various reactions such as nitriles, amides, and imines
  • for potential usage in thermal energy storage

Pittogrammi

FlameCorrosion

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Dam. 1 - Flam. Sol. 1 - Met. Corr. 1 - Skin Corr. 1A - Water-react 1

Codice della classe di stoccaggio

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

365.0 °F - closed cup

Punto d’infiammabilità (°C)

185 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificati d'analisi (COA)

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Complications from dual roles of sodium hydride as a base and as a reducing agent
Hesek D, et al.
The Journal of Organic Chemistry, 74(6), 2567-2570 (2009)
Ti-doped NaAlH4 as a hydrogen-storage material-preparation by Ti-catalyzed hydrogenation of aluminum powder in conjunction with sodium hydride
Bogdanovic B and Schwickardi M
Applied Physics. A, Materials Science & Processing, 72(2), 221-223 (2001)
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Articoli

Our research impacts on the hydrogen energy economy through the development of “smart” nanofilms for the protection of metal hydrides against air and moisture, while permitting release of hydrogen gas through these semi permeable nanofilms.

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.