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Sigma-Aldrich

Ruthenium(III) chloride hydrate

ReagentPlus®

Sinonimo/i:

Ruthenium trichloride

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About This Item

Formula condensata:
RuCl3 · xH2O
Numero CAS:
14898-67-0
Peso molecolare:
207.43 (anhydrous basis)
Numero CE:
233-167-5
Numero MDL:
MFCD00149844
Codice UNSPSC:
12352302
ID PubChem:
24852386
NACRES:
NA.23

Livello qualitativo

200

Nome Commerciale

ReagentPlus®

Forma fisica

powder and chunks

Composizione

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

Impiego in reazioni chimiche

reagent type: catalyst
core: ruthenium

Impurezze

≤0.1% Insoluble matter (C=1%, 25% HCl)

Stringa SMILE

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Descrizione generale

Ruthenium(III) chloride hydrate ReagentPlus® is a versatile and valuable compound in various scientific and industrial applications, particularly due to its catalytic properties and role in material science. Its ability to participate in numerous chemical reactions and processes makes it an essential reagent in both research and practical applications. It comes with black or grey color with insoluble matter ≤ 0.1 %; and % Ruthenium after reduction with Magnesium is 40.00 - 49.00 %.

Applicazioni

Ruthenium(III) chloride hydrate (RuCl₃·xH₂O) is a versatile compound with several applications across different fields. It can be used as a catalyst hydrogeneation, oxidation reachtions. For example, one of the study has found it as an efficient catalyst for the selective oxidation of fatty alcohols to aldehydes. Due to its excellent conductivity and ability to withstand higher temperature, the product is used in electronics as a precursor for thin film deposition. Thin films of ruthenium and its derivatives are used in the fabrication of memory devices, microelectromechanical systems (MEMS) and integrated circuits. It can be used in the preparation of electrodes for electrochemical cells due to its good conductivity and stability. Ruthenium(III) chloride hydrate is used in the synthesis of ruthenium nanoparticles, which have applications in catalysis, electronics, and material science. Ruthenium compounds are being researched for their potential use as anticancer agents due to their ability to bind to DNA and inhibit cell proliferation. In addition, ruthenium(III) chloride hydrate is utilized in the field of solar energy. It is used as a sensitizer in dye-sensitized solar cells (DSSCs). DSSCs are an alternative to traditional silicon-based photovoltaic cells with low cost and easy fabrication process. Ruthenium-based dyes absorb light and transfer electrons, initiating the energy conversion process in DSSCs.

Caratteristiche e vantaggi

Ruthenium(III) Chloride hydrate ReagentPlus® has been designed and tested keeping the requirements of research applications with low insoluble matters, specifications ensuring the material is suitable for high-performance applications and provides consistency in experimental and industrial processes.

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Avvertenze

Danger

Indicazioni di pericolo

H302,H314,H411

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ6100
MKCQ2849
MKCP8876
MKCP3042
MKCN0815

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TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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