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等級
reagent grade
品質等級
蒸汽壓力
<1 mmHg ( 20 °C)
化驗
95%
形狀
powder
pH值
1 (5 g/L)
mp
179-181 °C (subl.) (lit.)
SMILES 字串
ClP(Cl)(Cl)(Cl)Cl
InChI
1S/Cl5P/c1-6(2,3,4)5
InChI 密鑰
UHZYTMXLRWXGPK-UHFFFAOYSA-N
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一般說明
Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.
應用
Phosphorus pentachloride may be used in the synthesis of following compounds:
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
- benzenesulfonyl chloride
- malonic dinitrile
- aromatic sulfonyl chlorides
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
訊號詞
Danger
危險分類
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
標靶器官
Respiratory Tract
安全危害
儲存類別代碼
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類(WGK)
WGK 1
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Comprehensive Organic Functional Group Transformations II, 2 (1995)
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond (2005)
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems (2012)
Concise Encyclopedia Chemistry, 120-120 (1994)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Tetrahedron, 55(34), 10271-10282 (1999)
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