8.22340

Phosphorus pentachloride

for synthesis

• 别名: Phosphorus pentachloride, Phosphorus(V) chloride
• 经验公式（希尔记法）: Cl₅P
• CAS号: 10026-13-8
• 分子量: 208.24
• MDL號碼: MFCD00011439
• 分類程式碼代碼: 12352307
• 酶委員會索引編號: 233-060-3
• NACRES: NA.22

属性

• 蒸汽壓力: 0.016 hPa ( 20 °C)
• 品質等級: 200
• 化驗: ≥99.0% (argenometric)
• 形狀: crystalline solid
• 效力: 660 mg/kg LD₅₀, oral (Rat)
• pH值: 1 (5 g/L in H₂O, acidic)
• mp: 148 °C
• 密度: 2.1 g/cm³ at 20 °C
• 儲存溫度: 2-30°C
• InChI: 1S/Cl5P/c1-6(2,3,4)5
• InChI 密鑰: UHZYTMXLRWXGPK-UHFFFAOYSA-N

说明

應用

• Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).


• Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).


• Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).


• Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).

分析報告

Assay (argentometric): ≥ 99.0 %

安全信息

• 象形圖: GHS05,GHS06,GHS08
• 訊號詞: Danger
• 危險聲明: H302 - H314 - H330 - H373
• 防範說明: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• 危險分類: Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
• 標靶器官: Respiratory Tract
• 安全危害: EUH014 - EUH029
• 儲存類別代碼: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• 水污染物質分類（WGK）: WGK 1