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456055

Sigma-Aldrich

莰烯

95%

别名:

(±)-莰烯, 2,2-二甲基-3-亚甲基双环[2.2.1]庚烷, 2,2-二甲基-3-亚甲基降冰片烷, 2,2-二甲基-3-甲亚基双环[2.2.1]庚烷, 2-亚甲基-3,3-二甲基双环[2.2.1]庚烷, 3,3-二甲基-2-亚甲基降冰片烷, 3,3-二甲基-2-亚甲基降莰烷, DL-莰烯

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About This Item

经验公式（希尔记法）:
C10H16
CAS号:
79-92-5
分子量:
136.23
EC號碼:
201-234-8
MDL號碼:
MFCD00066603
分類程式碼代碼:
12352100
PubChem物質ID:
24869106
NACRES:
NA.22

化驗

95%

形狀

solid

bp

159-160 °C (lit.)

mp

48-52 °C (lit.)

密度

0.85 g/mL at 25 °C (lit.)

SMILES 字串

[H][C@]12CC[C@]([H])(C1)C(C)(C)C2=C

InChI

1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m0/s1

InChI 密鑰

CRPUJAZIXJMDBK-DTWKUNHWSA-N

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相关类别

一般說明

莰烯是双环单萜，是多种植物精油中的成分，包括月桃(Alpinia speciosa)、苍耳(Xanthium strumarium)叶、山松Pinus uncinata和Pinus uliginosa的松针。(5)

應用

莰烯作为反应剂的用途如下：
  • 通过二氧化硅负载磷钨酸催化的C2-C6脂肪酸液相酯化反应合成异冰片基羧酸酯。
  • 过氧化双月桂酰为引发剂，与N-羟基邻苯二甲酰亚胺和亚磷酸三乙酯通过分子间反马氏(anti-Markovnikov)氢胺化反应合成氢胺化莰烯。
  • H2O2为氧化剂，吡唑为路易斯碱加合物，通过甲基三氧化铼催化的环氧化反应合成莰烯氧化物。
  • 与醇通过阳离子交换树脂催化的烷氧化反应合成异冰片基烷醚。

訊號詞

Danger

危險聲明

H228,H319,H410

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

78.8 °F - DIN 51755 Part 1

閃點（°C）

26 °C - DIN 51755 Part 1

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCH6072
MKCG2794
MKCG3032
MKCG3104
MKCF5104

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Dendritic growth kinetics and structure II. Camphene.
Rubinstein ER and Glicksman ME.
Journal of Crystal Growth, 112(1), 97-110 (1991)
Javad Sharifi-Rad et al.
Molecules (Basel, Switzerland), 20(4), 7034-7047 (2015-04-22)
The chemical composition of the essential oil (EO) from fresh cocklebur (Xanthium strumarium L.) leaves was investigated by GC-MS. The antimicrobial activity of the EO was tested against Gram-positive and Gram-negative bacteria and fungi. Scolicidal activity was assayed against Echinococcus
Radosław Bonikowski et al.
Natural product communications, 10(2), 371-373 (2015-04-30)
The compositions of mountain pine (Pinus uncinata) and peat-bog pine (P. uliginosa) needle essential oils were investigated. Enantiomeric compositions of selected monoterpene hydrocarbons were also examined. Respectively, fifty-three and seventy-six components of the essential oils were identified using GC-MS and
Lakshmi Vasireddy et al.
PloS one, 13(8), e0201835-e0201835 (2018-08-03)
Members of the Burkholderia cepacia complex (Bcc) are an important cause of opportunistic or nosocomial infections that may be hard to treat due to a high incidence of multidrug resistance. We characterised a collection of 51 clinical isolates from this
A Sunesson et al.
Applied and environmental microbiology, 61(8), 2911-2918 (1995-08-01)
Five fungal species, Aspergillus versicolor, Penicillium commune, Cladosporium cladosporioides, Paecilomyces variotii, and Phialophora fastigiata, were cultivated on two media, malt extract agar and dichloran glycerol agar. Culture flasks provided with inlet and outlet tubes were used and purified, and humidified
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实验方案

Essential Oil on SLB®-5ms

Cinnamoµm Camphor, also known as the camphor tree, is grown in several parts of the world including Japan, Taiwan, and Australia. Camphor, which is used in medicinal and cosmetic preparations, is derived from the leaves and wood of this tree.

GC Analysis of Peppermint Essential Oil on SLB®-IL59

Cymene; 4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran; Linalool; Menthol; Menthone; Menthyl acetate; Germacrene D; Bicyclogermacrene; Thymol

GC Analysis of Lemon Essential Oil on SLB®-IL59, 3 °C/min Oven Ramp

-α-Bergamotene; β-Bisabolene; α-Terpineol; Neryl acetate; Geranyl acetate; Neral; Geranial

GC Analysis of Lemon Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 µM), Fast GC Analysis

-3,7-Dimethyl-2,6-octadien-1-ol; Neral; Geraniol; Geranial; Undecanal; Citronellyl acetate; Neryl acetate; 3,7-Dimethyl-2,6-octadienyl acetate; 1-Tetradecene; Tetradecane; α-Bisabolol

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