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310115

Sigma-Aldrich

三氯化磷

99.999% trace metals basis

别名:

氯化磷(III)

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About This Item

线性分子式:
PCl3
CAS号:
7719-12-2
分子量:
137.33
Beilstein:
969177
EC號碼:
231-749-3
MDL號碼:
MFCD00011438
分類程式碼代碼:
12352300
PubChem物質ID:
24858774
NACRES:
NA.23

蒸汽密度

4.75 (vs air)

蒸汽壓力

100 mmHg ( 20 °C)
125 mmHg ( 25 °C)
385 mmHg ( 55 °C)

化驗

99.999% trace metals basis

形狀

liquid

折射率

n20/D 1.5148 (lit.)

bp

74-78 °C (lit.)

mp

−112 °C (lit.)

密度

1.574 g/mL at 20 °C (lit.)

SMILES 字串

ClP(Cl)Cl

InChI

1S/Cl3P/c1-4(2)3

InChI 密鑰

FAIAAWCVCHQXDN-UHFFFAOYSA-N

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訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation

標靶器官

Respiratory Tract

安全危害

EUH014,EUH029

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
MKCM9390
SHBK4582
SHBF7461V
SHBF3024V
SHBC8044V

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Action of phosphorus pentachloride on p-sulphonamido benzoic acid.
A D KEMP
Nature, 159(4041), 509-509 (1947-04-12)
S Wason et al.
The American journal of medicine, 77(6), 1039-1042 (1984-12-01)
A railroad accident in Somerville, Massachusetts, led to spillage of phosphorus trichloride liquid. Attempted clean-up with water led to the liberation of phosphorus trichloride, phosphoric acid, hydrochloric acid, and phosphorus oxides. Seventeen people exposed to this mixture were studied. Patients
[X-ray analysis of lung damage caused by PCl3 inhalation].
Chun-fang Li et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 23(4), 308-309 (2005-09-29)
Núria Mont et al.
Molecular diversity, 13(1), 39-45 (2008-11-28)
A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, affords the corresponding 2-hydro-4-oxo-pyridopyrimidine 14, which is converted
D Zicane et al.
International journal of peptide and protein research, 48(1), 56-58 (1996-07-01)
N-Formylpyroglutamic acid-7-amido-4-methylcoumarine and pyroglutamyl-pyroglutamic acid-7-amido-4-methylcoumarin are the major products in the synthesis of pyroglutamic acid-7-amido-4-methylcoumarin by phosphorus pentachloride in dimethylformamide and dicyclohexylcarbodiimide under pyridine activation.
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