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Merck
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文件

687502

Sigma-Aldrich

四异丙醇钛

packaged for use in deposition systems

别名:

TTIP, 钛酸异丙酯

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About This Item

线性分子式:
Ti[OCH(CH3)2]4
CAS号:
546-68-9
分子量:
284.22
Beilstein:
3679474
EC號碼:
208-909-6
MDL號碼:
MFCD00008871
分類程式碼代碼:
12352107
PubChem物質ID:
329761133

品質等級

100

化驗

99.999%

形狀

liquid

反應適用性

core: titanium
reagent type: catalyst

折射率

n20/D 1.464 (lit.)

bp

232 °C (lit.)

mp

14-17 °C (lit.)

密度

0.96 g/mL at 20 °C (lit.)

SMILES 字串

CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI

1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

InChI 密鑰

VXUYXOFXAQZZMF-UHFFFAOYSA-N

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相关类别

一般說明

基础材料的原子序数：22钛

應用

前体包装用于沉积系统
通过两步溶胶-凝胶法从钛酸异丙酯形成的新型金属氧化物/膦酸盐杂化物。 钛酸锶钡薄膜起始物质。用于合成介孔钛硅材料，后者是一种可能用于放射废物清洁的离子交换材料。 参与合成TiO2纳米晶体紫精电子受体复合体构成的异超分子，后者的光诱导电子转移特性已经过研究。

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Warning

危險聲明

H226 - H319 - H336

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

標靶器官

Central nervous system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

105.8 °F - Pensky-Martens closed cup

閃點（°C）

41 °C - Pensky-Martens closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Catalytic asymmetric aryl transfer reactions to aldehydes with Grignard reagents as the aryl source.
Yusuke Muramatsu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(34), 10560-10563 (2008-10-31)
Manas K Panda et al.
Dalton transactions (Cambridge, England : 2003), 39(9), 2428-2440 (2010-02-18)
Controlled oxidation of organic sulfides to sulfoxides under ambient conditions has been achieved by a series of titanium isopropoxide complexes that use environmentally benign H(2)O(2) as a primary oxidant. Specifically, the [N,N'-bis(2-oxo-3-R(1)-5-R(2)-phenylmethyl)-N,N'-bis(methylene-R(3))-ethylenediamine]Ti(O(i)Pr)(2) [R(1) = t-Bu, R(2) = Me, R(3) =
Laszlo Sipos et al.
Biomacromolecules, 6(5), 2570-2582 (2005-09-13)
A poly(styrene-b-isobutylene-b-styrene) (SIBS) triblock polymer is employed as the polymer drug carrier for the TAXUS Express2 Paclitaxel-Eluting Coronary Stent system (Boston Scientific Corp.). It has been shown that the release of paclitaxel (PTx) from SIBS can be modulated by modification
Alfred J Wooten et al.
Organic letters, 9(3), 381-384 (2007-01-26)
[reaction: see text] We report the catalytic asymmetric allylation of ketones under highly concentrated reaction conditions with a catalyst generated from titanium tetraisopropoxide and BINOL (1:2 ratio) in the presence of isopropanol. This catalyst promotes the addition of tetraallylstannane to
Henrique Antonio Mendonça Faria et al.
Materials science & engineering. C, Materials for biological applications, 56, 260-268 (2015-08-08)
The structural and electronic properties of titanium oxide nanotubes (TiO2) have attracted considerable attention for the development of therapeutic devices and imaging probes for nanomedicine. However, the fluorescence response of TiO2 has typically been within ultraviolet spectrum. In this study
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