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Merck

536040

Sigma-Aldrich

4-4′-二甲氧基-2-2′-联吡啶

greener alternative

97%

别名:

4,4′-二甲氧基-2,2′-联吡啶

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About This Item

经验公式(希尔记法):
C12H12N2O2
CAS号:
分子量:
216.24
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

168-171 °C (lit.)

環保替代類別

SMILES 字串

COc1ccnc(c1)-c2cc(OC)ccn2

InChI

1S/C12H12N2O2/c1-15-9-3-5-13-11(7-9)12-8-10(16-2)4-6-14-12/h3-8H,1-2H3

InChI 密鑰

IMEVSAIFJKKDAP-UHFFFAOYSA-N

一般說明

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品已增强催化作用。点击此处,查看更多详情。

應用

4-4′-二甲氧基-2-2'-联吡啶可用作过渡金属配合物制备中的配体。

在有氧条件下醇的绿色氧化的配体。

铜(I)/ABNO催化的有氧醇氧化:减轻Cu/TEMPO催化剂系统的空间和电子约束

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析证书(COA)

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Julie Urgiles et al.
Dalton transactions (Cambridge, England : 2003), 46(41), 14256-14263 (2017-10-11)
Reactions of K
Photochemical isomerization of trans- to cis-[RuCl2(dppb)(4,4'-X2-2,2'-bipy)](X=-H,-NO2,-Me,-COOH,-SMe,-O=SMe,-Cl,-OMe) complexes.
Santiago MO, et al.
Polyhedron, 22(24), 3205-3211 (2003)
Synthesis and characterization of a new family of luminescent cis-(4, 4'-X2-5, 5'-Y2-2, 2'-bipyridine) 2Os (CO) Cl (PF6) complexes (X= NEt2, OMe, Me, H, Cl, Y= H; X= H, Y= Me; X= Y= Me): control of excited-state properties by bipyridyl substituents.
Della CL, et al.
Inorganic Chemistry, 29(15), 2792-2798 (1990)
Efficient osmium sensitizers containing 2,2'-bipyridine-4,4'-bisphosphonic acid ligand.
Zabri H, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 166(1), 99-106 (2004)
Katia M Oliveira et al.
Journal of inorganic biochemistry, 176, 66-76 (2017-09-04)
New Ru(II) complexes with lawsone (law) characterized as trans-[Ru(law)(PPh

商品

Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reaction.

Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reaction.

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