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品質等級
化驗
95%
折射率
n20/D 1.668 (lit.)
bp
269 °C/752.5 mmHg (lit.)
密度
1.629 g/mL at 25 °C (lit.)
SMILES 字串
Brc1csc2ccccc12
InChI
1S/C8H5BrS/c9-7-5-10-8-4-2-1-3-6(7)8/h1-5H
InChI 密鑰
SRWDQSRTOOMPMO-UHFFFAOYSA-N
一般說明
3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.
應用
3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
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Reactions of bromothianaphthenes with piperidine. Reinvestigation.
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