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Merck

440442

Sigma-Aldrich

O-(三甲基硅基)羟胺

technical grade, 90%

别名:

氨氧基三甲基硅烷

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About This Item

线性分子式:
(CH3)3SiONH2
CAS号:
分子量:
105.21
Beilstein:
2035893
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

品質等級

化驗

90%

形狀

liquid

折射率

n20/D 1.405 (lit.)

bp

98-100 °C (lit.)

密度

0.86 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C[Si](C)(C)ON

InChI

1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3

InChI 密鑰

AEKHNNJSMVVESS-UHFFFAOYSA-N

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一般說明

O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.

應用

O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

53.6 °F - closed cup

閃點(°C)

12 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ying Fu et al.
Organic & biomolecular chemistry, 10(38), 7669-7672 (2012-08-14)
A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these
Chemoselective addition of organometallics to oxime ethers.
Tavakol H,et al.
Journal of Organometallic Chemistry, 692(10), 1924-1927 (2007)

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