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Merck

419532

Sigma-Aldrich

2-甲基烯丙基氯化镁 溶液

0.5 M in THF

别名:

(2-Methyl-2-propenyl)magnesium chloride, Chloro(2-methyl-2-propenyl)magnesium, Chloro(2-methylallyl)magnesium, Methallylmagnesium chloride

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About This Item

线性分子式:
H2C=C(CH3)CH2MgCl
CAS号:
分子量:
114.86
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

反應適用性

reaction type: Grignard Reaction

品質等級

濃度

0.5 M in THF

bp

65-67 °C

密度

0.915 g/mL at 25 °C

SMILES 字串

CC(=C)C[Mg]Cl

InChI

1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1

InChI 密鑰

BJVFGWYBOLMUEM-UHFFFAOYSA-M

應用

2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.

包裝

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

標靶器官

Respiratory system

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

-5.8 °F - closed cup

閃點(°C)

-21 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Allyldicyclopentadienyltitanium (III) and (DI) methylallyl homologues.
Martin H A and Jellinek F
Journal of Organometallic Chemistry, 8(1), 115-128 (1967)
The total synthesis of (−)-aplysin via a lithiation?borylation?propenylation sequence.
Fletcher C J, et al.
Tetrahedron, 68(37), 7598-7604 (2012)
B List et al.
Proceedings of the National Academy of Sciences of the United States of America, 95(26), 15351-15355 (1998-12-23)
The synthesis of novel fluorogenic retro-aldol substrates for aldolase antibody 38C2 is described. These substrates are efficiently and specifically processed by antibody aldolases but not by natural cellular enzymes. Together, the fluorogenic substrates and antibody aldolases provide reporter gene systems
?Classical carbonyl reactivity enables a short synthesis of the core structure of acutumine?
Moreau.JR and Sorensen.JE
Tetrahedron, 63(28), 6446-6453 (2007)

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