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形狀
solution
品質等級
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
密度
0.940 g/mL at 25 °C
官能基
allyl
SMILES 字串
Br[Mg]CCCC=C
InChI
1S/C5H9.BrH.Mg/c1-3-5-4-2;;/h3H,1-2,4-5H2;1H;/q;;+1/p-1
InChI 密鑰
LHTUYNSQNJOCCB-UHFFFAOYSA-M
應用
4-Pentenylmagnesium bromide is a general Grignard reagent used in the total synthesis of (−)-sarain A, (−)-salicylihalamide A and (+)-erysotramidine. It is also used in the synthesis of hexa-peri-hexabenzocoronene cyclophane.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
11.8 °F - closed cup
閃點（°C）
-11.2 °C - closed cup
其他客户在看
Total synthesis of (−)-salicylihalamide A and related congeners.
Smith III A B, et al.
Tetrahedron, 58(32), 6455-6471 (2002)
A Hexa-peri-hexabenzocoronene Cyclophane: An Addition to the Toolbox for Molecular Electronics.
Watson M D, et al.
Journal of the American Chemical Society, 126(5), 1402-1407 (2004)
Total synthesis of (−)-Sarain A.
Becker M H, et al.
Journal of the American Chemical Society, 129(39), 11987-12002 (2007)
New approaches for the synthesis of erythrinan alkaloids.
Zhang F, et al.
Organic & Biomolecular Chemistry, 7(9), 1963-1979 (2009)
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