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蒸汽密度
>1 (vs air)
蒸汽壓力
6.96 psi ( 20 °C)
化驗
≥98.5% (GC)
折射率
n20/D 1.376 (lit.)
n20/D 1.377
bp
41 °C (lit.)
mp
−115 °C (lit.)
密度
0.653 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)(C)C=C
InChI
1S/C6H12/c1-5-6(2,3)4/h5H,1H2,2-4H3
InChI 密鑰
PKXHXOTZMFCXSH-UHFFFAOYSA-N
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一般說明
3,3-二甲基-1-丁烯通过氯促进的 Ag（111）氧原子选择性地氧化成相应的环氧化物。3,3-二甲基-1-丁烯使用链行走 Pd-二亚胺催化剂与乙烯共聚。3,3-二甲基-1-丁烯（叔丁基乙烯）的阳离子聚合是在 -31 至-130°C 的温度范围内，使用 AlCl3 催化剂在氯乙烷溶剂中进行的。
應用
- Quantification of relevant Brønsted acid sites on Cl-doped alumina catalysts for the isomerization of olefins： 该研究探索了Cl掺杂氧化铝对3,3-二甲基-1-丁烯异构化反应的催化活性，说明了异构化效率与催化剂特定Brønsted酸位点的线性关系。(Q Rivet, R Beucher, F Morfin, T Nardin, D Farrusseng, Journal of Catalysis, 2023)。
訊號詞
Danger
危險聲明
危險分類
Asp. Tox. 1 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
17.6 °F - closed cup
閃點（°C）
-8 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves
其他客户在看
Cationic isomerization polymerization of 3, 3-dimethyl-1-butene.
Kennedy JP, et al.
Makromol. Chem., 79(1), 109-121 (1964)
Molecular mechanism of alkene epoxidation: A model study with 3, 3-dimethyl-1-butene on Ag (111).
Mukoid C, et al.
Catalysis Letters, 4(1), 57-61 (1990)
Peng Xiang et al.
Macromolecular rapid communications, 31(12), 1083-1089 (2011-05-19)
In this Communication, the copolymerization of ethylene with a sterically hindered α-olefin comonomer, γ-trisubstituted 3,3-dimethyl-1-butene (DMB), using a chain-walking Pd-diimine catalyst, [(ArNC(Me)(Me)CNAr)Pd(CH(3) )(NCMe)]SbF(6) (Ar2,6-(iPr)(2) C(6) H(3) ) (1) is reported. In spite of its high steric bulkiness in the close
商品
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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