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379239

Sigma-Aldrich

三甲基铝 溶液

2.0 M in heptane

别名:

Aluminum trimethanide solution

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About This Item

线性分子式:
(CH3)3Al
CAS号:
75-24-1
分子量:
72.09
Beilstein:
3587197
MDL號碼:
MFCD00008252
分類程式碼代碼:
12352103
PubChem物質ID:
24863230
NACRES:
NA.22

形狀

liquid

品質等級

100

濃度

2.0 M in heptane

密度

0.693 g/mL at 25 °C

SMILES 字串

C[Al](C)C

InChI

1S/3CH3.Al/h3*1H3;

InChI 密鑰

JLTRXTDYQLMHGR-UHFFFAOYSA-N

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相关类别

應用

Trimethylaluminum can be used in the synthesis of methylaluminoxane (MAO), a precatalyst for olefin polymerization. It is a precursor for the preparation of a wide range of organoaluminium such as dimethylaluminum chloride and bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]-octane (DABAL-Me3).

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

安全危害

EUH014

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

-0.4 °F - closed cup

閃點（°C）

-18 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
STBJ9750
STBJ7331
STBJ4244
SHBK0395
STBH5115

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Remarkably Stable (Me3Al) 2? DABCO and Stereoselective Nickel?Catalyzed AlR3 (R= Me, Et) Additions to Aldehydes.
Biswas K, et al.
Angewandte Chemie (International Edition in English), 44(15), 2232-2234 (2005)
Gasometric titration for dimethylaluminum chloride analysis.
Wang L, et al.
Journal of Pharmaceutical and Biomedical Analysis, 125, 110-113 (2016)
Methylaluminoxane: synthesis, characterization and catalysis of ethylene polymerization.
Reddy S S, et al.
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J L L Robinson et al.
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