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Merck

236330

Sigma-Aldrich

对甲苯磺酰胺

ReagentPlus®, ≥99%

别名:

4-Methylbenzene-1-sulfonamide, p-Tosylamide

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About This Item

线性分子式:
CH3C6H4SO2NH2
CAS号:
分子量:
171.22
Beilstein:
472689
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

產品線

ReagentPlus®

化驗

≥99%

形狀

solid

mp

134-137 °C (lit.)

SMILES 字串

Cc1ccc(cc1)S(N)(=O)=O

InChI

1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)

InChI 密鑰

LMYRWZFENFIFIT-UHFFFAOYSA-N

基因資訊

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一般說明

研究了氰甲基三丁基磷 (CMBP) 介导的 甲苯磺酰胺与醇的反应

應用

p -甲苯磺酰胺已被用作:
  • 四丁基氟化铵 (TBAF) 催化乙烯基氮丙啶开环反应中的亲核试剂
  • 己内酰胺二铑 (II) 催化烯烃氮杂环丙烷化反应的试剂

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

395.6 °F - closed cup

閃點(°C)

202 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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E Simone et al.
Lab on a chip, 18(15), 2235-2245 (2018-06-28)
In this work, a novel multi-microfluidic crystallization platform called MMicroCryGen is presented, offering a facile methodology for generating individual crystals for fast and easy screening of the polymorphism and crystal habit of solid compounds. The MMicroCryGen device is capable of
Mitsunobu-type alkylation of p-toluenesulfonamide. A convenient new route to primary and secondary amines.
Tsunoda T, et al.
Tetrahedron Letters, 37(!4), 2457-2458 (1996)
Arthur J Catino et al.
Organic letters, 7(13), 2787-2790 (2005-06-17)
[reaction: see text] A mild, efficient, and selective aziridination of olefins catalyzed by dirhodium(II) caprolactamate [Rh(2)(cap)(4).2CH(3)CN] is described. Use of p-toluenesulfonamide (TsNH(2)), N-bromosuccinimide (NBS), and potassium carbonate readily affords aziridines in isolated yields of up to 95% under extremely mild
An efficient FeCl3 -catalyzed amidation reaction of secondary benzylic and allylic alcohols with carboxamides or p-toluenesulfonamide.
Jana U, et al.
Tetrahedron Letters, 42(37), 6433-6435 (2001)
Charles H Reynolds et al.
Journal of medicinal chemistry, 51(8), 2432-2438 (2008-04-03)
Ligand efficiency (i.e., potency/size) has emerged as an important metric in drug discovery. In general, smaller, more efficient ligands are believed to have improved prospects for good drug properties (e.g., bioavailability). Our analysis of thousands of ligands across a variety

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