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Merck

105902

Sigma-Aldrich

对甲苯磺酰胺

reagent grade, 97%

别名:

4-Methylbenzene-1-sulfonamide, p-Tosylamide

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About This Item

线性分子式:
CH3C6H4SO2NH2
CAS号:
分子量:
171.22
Beilstein:
472689
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

reagent grade

品質等級

化驗

97%

形狀

solid

mp

134-137 °C (lit.)

溶解度

DMSO: soluble

官能基

sulfonamide

SMILES 字串

Cc1ccc(cc1)S(N)(=O)=O

InChI

1S/C7H9NO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)

InChI 密鑰

LMYRWZFENFIFIT-UHFFFAOYSA-N

基因資訊

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一般說明

在FeCl3催化下,对甲苯磺酰胺可与苄基和烯丙基醇发生直链取代反应。它被用作四丁基氟化铵(TBAF)催化的乙烯基氮丙啶开环反应的亲核试剂

應用

使用对甲苯磺酰胺可制备用于合成乙基-6-苯基-1-甲苯磺酰基-1,2,5,6-四氢吡啶-3-羧酸乙酯所需的前体

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

395.6 °F - closed cup

閃點(°C)

202 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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PHOSPHINE-CATALYZED [4+2] ANNULATION: SYNTHESIS OF ETHYL 6-PHENYL-1-TOSYL-1,2,5,6-TETRAHYDROPYRIDINE-3-CARBOXYLATE.
Kui Lu et al.
Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals, 2009(86), 212-224 (2010-02-18)
An efficient FeCl3 -catalyzed amidation reaction of secondary benzylic and allylic alcohols with carboxamides or p-toluenesulfonamide.
Jana U, et al.
Tetrahedron Letters, 42(37), 6433-6435 (2001)
Charles H Reynolds et al.
Journal of medicinal chemistry, 51(8), 2432-2438 (2008-04-03)
Ligand efficiency (i.e., potency/size) has emerged as an important metric in drug discovery. In general, smaller, more efficient ligands are believed to have improved prospects for good drug properties (e.g., bioavailability). Our analysis of thousands of ligands across a variety
Yang Yang et al.
Organic letters, 13(20), 5608-5611 (2011-09-16)
BF(3)·OEt(2)-catalyzed direct cyanation of indoles and pyrroles using a less toxic, bench-stable, and easily handled electrophilic cyanating agent N-cyano-N-phenyl-para-toluenesulfonamide (NCTS) affords 3-cyanoindoles and 2-cyanopyrroles in good yields with excellent regioselectivity. The substrate scope is broad with respect to indoles and
Daniela Vullo et al.
Bioorganic & medicinal chemistry letters, 15(4), 971-976 (2005-02-03)
The inhibition of a newly cloned human carbonic anhydrase (CA, EC 4.2.1.1), isozyme VII (hCA VII), has been investigated with a series of aromatic and heterocyclic sulfonamides, including some of the clinically used derivatives (acetazolamide, methazolamide, ethoxzolamide, dichlorophenamide, dorzolamide, brinzolamide

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