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品質等級
反應適用性
reaction type: Grignard Reaction
濃度
2.0 M in THF
密度
1.031 g/mL at 25 °C
SMILES 字串
Cl[Mg]Cc1ccccc1
InChI
1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI 密鑰
NRAFPLGJPPJUNB-UHFFFAOYSA-M
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一般說明
氯苄镁是一种有机金属化合物，可用作Lewis酸和强碱。
應用
苄基氯化镁（格利雅试剂）可用作烷基化试剂：
- 烷基化喹啉基功能化Cp−铬(III)复合物，以作为前体用于制备活性烯烃聚合催化剂。
- 合成2,3-二取代苯并吡喃-4-酮、6-氯代-8- 甲基嘌呤衍生物和苯基丙氨酸衍生物。
訊號詞
Danger
危險分類
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
1.4 °F - closed cup
閃點（°C）
-17 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Dichotomy in regioselective cross-coupling reactions of 6, 8-dichloropurines with phenylboronic acid and methylmagnesium chloride: synthesis of 6, 8-disubstituted purines
Hocek M, et al.
Synthesis, 2004(06), 889-894 (2004)
Quinolyl-functionalised Cp-chromium polymerisation catalysts: synthesis and crystal structures of alkylation products
Enders M, et al.
Journal of Organometallic Chemistry, 687(1), 125-130 (2003)
A novel synthesis of 2, 3-disubstituted benzopyran-4-ones and application to the solid phase
Harikrishnan LS and Showalter HD H
Tetrahedron, 56(4), 515-519 (2000)
A facile three-step synthesis of 1, 2-amino alcohols using the Ellman homochiral tert-butylsulfinamide
Barrow JC, et al.
Tetrahedron Letters, 42(11), 2051-2054 (2001)
Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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