302759

苄基氯化镁 溶液

1.0 M in diethyl ether

• 别名: (Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium
• 线性分子式: C₆H₅CH₂MgCl
• CAS号: 6921-34-2
• 分子量: 150.89
• Beilstein: 878506
• MDL號碼: MFCD00000469
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24858271
• NACRES: NA.22

属性

• 品質等級: 100
• 反應適用性: reaction type: Grignard Reaction
• 濃度: 1.0 M in diethyl ether
• 密度: 0.794 g/mL at 25 °C
• SMILES 字串: Cl[Mg]Cc1ccccc1
• InChI: 1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
• InChI 密鑰: NRAFPLGJPPJUNB-UHFFFAOYSA-M

说明

一般說明

Benzylmagnesium chloride is a versatile Grignard reagent frequently used in organic synthesis. It can be used as a reagent in the addition reaction with carbonyl compounds, nitriles, epoxides, and alkyl halides to synthesize various alcohols, amines, and ketones. Additionally, it is also used in reductions, cross-coupling, allylation and alkylation reactions.

應用

Benzylmagnesium chloride solution (1.0 M in diethyl ether) is used as a reagent to provide the benzyl group required for the synthesis of the desired sulfonic acid-functionalized alkoxysilane. It is also used in the anionic polymerization of styrene to form styrenyl magnesium chloride, which is further used as an initiator in the synthesis of polyolefin-block-polystyrene block copolymers.

安全信息

• 象形圖: GHS02,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225 - H302 - H314 - H336
• 防範說明: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Central nervous system
• 安全危害: EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: -40.0 °F - closed cup
• 閃點（°C）: -40 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter