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Merck

219584

Sigma-Aldrich

2,6-二叔丁基吡啶

≥97%

别名:

2,6-二叔丁基吡啶, 2,6-双(1,1-二甲基乙基)吡啶

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About This Item

经验公式(希尔记法):
C13H21N
CAS号:
分子量:
191.31
Beilstein:
125886
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥97%

形狀

liquid

折射率

n20/D 1.473 (lit.)

bp

100-101 °C/23 mmHg (lit.)

密度

0.852 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CC(C)(C)c1cccc(n1)C(C)(C)C

InChI

1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3

InChI 密鑰

UWKQJZCTQGMHKD-UHFFFAOYSA-N

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一般說明

2,6-二--叔 -丁基吡啶与四苯基卟啉铁阳离子自由基的反应性已通过质子 NMR 光谱学进行了研究。2,6-二--丁基吡啶与碘甲烷和氟磺酸甲酯在高压下的反应已有报道

應用

以 2,6-二- 叔丁基吡啶为质子捕获剂,研究了异丁烯的活性聚合。并与硝酸铈铵在 α-醛的烯醇化生成 1,4-二羰基系统

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

159.8 °F - closed cup

閃點(°C)

71 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Reactions of crowded molecules under high pressure. Reactions of 2, 6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure.
Okamoto Y and Lee KI.
Journal of the American Chemical Society, 97(!4), 4015-4018 (1975)
J. Macromol. Sci., Pure Appl. Chem., A29, 639-639 (1992)
Krystyna Rachlewicz et al.
Inorganic chemistry, 35(5), 1136-1147 (1996-02-28)
The reactivity of iron(III) tetraphenylporphyrin pi-cation radical (TPP(*))Fe(III)(ClO(4))(2), (1-1) iron(III) tetra-p-tolylporphyrin pi-cation radical (TTP(*))Fe(III)(ClO(4))(2) (1-2) and iron(III) tetramesitylporphyrin pi-cation radical (TMP(*))Fe(III)(ClO(4))(2) (1-3) complexes with 2,4,6-collidine, 2,3,6-collidine, 2-picoline, 2,6-di-tert-butylpyridine, and 2,6-dibromopyridine has been examined by (1)H NMR spectroscopy in dichloromethane-d(2) solution
Karolina A Tarach et al.
ChemSusChem, 12(3), 633-638 (2018-12-07)
A new theoretical and practical framework has been developed through operando study of the zeolite catalytic cracking of low-density polyethylene (as a model reaction) under reaction conditions. Results show that microporous ZSM-5 gives rise to less cracking products. Hierarchical ZSM-5
Living carbocationic polymerization of isobutylene with blocked bifunctional initiators in the presence of di-tert-butylpyridine as a proton trap.
Gyor M, et al.
J. Macromol. Sci., Pure Appl. Chem., 29(8), 639-653 (1992)

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