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品質等級
化驗
97%
形狀
liquid
包含
~0.1% hydroquinone as stabilizer
雜質
3% benzene
折射率
n20/D 1.472 (lit.)
bp
88-89 °C (lit.)
密度
0.847 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
C1C=CCC=C1
InChI
1S/C6H8/c1-2-4-6-5-3-1/h1-2,5-6H,3-4H2
InChI 密鑰
UVJHQYIOXKWHFD-UHFFFAOYSA-N
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一般說明
1,4-环己二烯是催化加氢反应的有效氢供体。它能迅速地用氢取代N-苄氧基氨基甲酸酯、苄酯、苄醚和苄胺的苄基。在钌 (II)-三苯基膦催化剂存在下在高温下形成苯。
應用
以1,4-环己二烯 (1,4-CHD) 为研究对象,研究了1,4-CHD 在强激光脉冲照射下的重碎裂形成母离子的过程。
用于电子转移介导的开环反应中形成的自由基中间体的还原
訊號詞
Danger
危險分類
Carc. 1A - Flam. Liq. 2 - Muta. 1B - STOT RE 2
標靶器官
Blood
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
19.4 °F - closed cup
閃點(°C)
-7 °C - closed cup
其他客户在看
Rapid removal of protecting groups from peptides by catalytic transfer hydrogenation with 1, 4-cyclohexadiene.
The Journal of Organic Chemistry, 43(21), 4194-4196 (1978)
A key factor in parent and fragment ion formation on irradiation with an intense femtosecond laser pulse.
Chemical Physics Letters, 342(5), 563-570 (2001)
Organometallics, 25, 5456-5456 (2006)
Organic letters, 14(23), 6016-6019 (2012-11-15)
Asymmetric bromolactonization of prochiral cyclohexadiene derivatives with N-bromosuccimide proceeded in the presence of (DHQD)(2)PHAL as a chiral catalyst to afford the corresponding bromolactones with up to 93% ee. This reaction was also applicable to the kinetic resolution of a racemic
The journal of physical chemistry. A, 113(25), 6955-6963 (2009-06-06)
A quantitative understanding of the thermochemistry of cyclohexadienyl radical and 1,4-cyclohexadiene is beneficial for diverse areas of chemistry. Given the interest in these two species, it is surprising that more detailed thermodynamic data concerning the homolytic C-H bond enthalpies of
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