402990

Iodine monochloride

ACS reagent, 1.10±0.1 I/Cl ratio basis

• Sinonimo/i: Chloroiodide
• Formula condensata: ICl
• Numero CAS: 7790-99-0
• Peso molecolare: 162.36
• Numero CE: 232-236-7
• Numero MDL: MFCD00011354
• Codice UNSPSC: 12352300
• ID PubChem: 329755974
• NACRES: NB.24

Proprietà

• Grado: ACS reagent
• Forma fisica: solid or liquid
• Impurezze: ≤0.005% insolubles
• P. eboll.: 97.4 °C (lit.)
• Solubilità: acetic acid: soluble(lit.); acetone: soluble(lit.); alcohol: soluble(lit.); carbon disulfide: soluble(lit.)
• Densità: 3.24 g/mL at 25 °C (lit.)
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: ClI
• InChI: 1S/ClI/c1-2; QZRGKCOWNLSUDK-UHFFFAOYSA-N

Descrizione

Descrizione generale

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

Applicazioni

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.

Iodine monochloride may be used in the synthesis of the following:

• 2-(4-haloisoquinolin-1-yl)ethanol derivatives
• 5-iodosalicylaldehydes
• 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
• (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
• (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol

Informazioni sulla sicurezza

• Pittogrammi: GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H314,H335
• Consigli di prudenza: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classi di pericolo: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 8B - Non-combustible corrosive hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable