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452335

Sigma-Aldrich

Tin(II) chloride

anhydrous, powder, ≥99.99% trace metals basis

Sinonimo/i:

Stannous chloride

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About This Item

Formula condensata:
SnCl2
Numero CAS:
Peso molecolare:
189.62
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.21

Grado

anhydrous

Livello qualitativo

Tensione di vapore

33 hPa (~429 °C)

Saggio

≥99.99% trace metals basis

Forma fisica

powder

Impiego in reazioni chimiche

reagent type: catalyst
core: tin

pH

2.18 (20 °C)

P. eboll.

606 °C
652 °C (lit.)

Punto di fusione

246 °C (lit.)

Solubilità

water: soluble 1780 g/L at 10 °C

Stringa SMILE

Cl[SnH2]Cl

InChI

1S/2ClH.Sn/h2*1H;/q;;+2/p-2
AXZWODMDQAVCJE-UHFFFAOYSA-L

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Descrizione generale

Tin(II) chloride (SnCl2), also known as stannous chloride, is commonly used as a reducing agent.

Applicazioni

Synthesis of tin(IV) octaethylcorroles was accomplished with this reagent. These new compounds exhibit reversible oxidation only at the conjugated ring system, not at the metal center.
Tin(II) chloride (SnCl2) has been used to label compounds with 99mtechnetium (99mTc).

Avvertenze

Danger

Classi di pericolo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Organi bersaglio

Cardio-vascular system, Respiratory system

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Jae-Ho Lee et al.
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Inorganic chemistry, 37(18), 4573-4577 (2001-10-24)
Two Sn(IV) corroles were synthesized and electrochemically examined. The investigated compounds are represented as (OEC)Sn(C(6)H(5)) and (OEC)SnCl, where OEC = trianion of 2,3,7,8,12,13,17,18-octaethylcorrole. (OEC)Sn(C(6)H(5)) represents the first example of a sigma-bonded metallocorrole which does not undergo a metal-centered electrode reaction.
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