913219
(S,S)-BABIBOP
Sinonimo/i:
(3S,3′S)-3,3′-Di-tert-butyl-2,2′,3,3′-tetrahydro-4,4′-bibenzo[d][1,3]oxaphosphole
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About This Item
Formula empirica (notazione di Hill):
C22H28O2P2
Numero CAS:
Peso molecolare:
386.40
Codice UNSPSC:
12352200
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Stato
powder
Purezza ottica
ee: ≥99% (HPLC)
Impiego in reazioni chimiche
reagent type: ligand
Gruppo funzionale
phosphine
Applicazioni
(S,S)-BABIBOP is a P-chiral biaryl biphosphorus ligand used in Pd, Cu, and Rh-catalyzed asymmetric hydrogenations.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
Note legali
Sold in collaboration with Zejun Pharmaceuticals
Prodotti correlati
N° Catalogo
Descrizione
Determinazione del prezzo
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
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Certificati d'analisi (COA)
Lot/Batch Number
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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.
Guisheng Li et al.
Organic letters, 20(7), 1725-1729 (2018-03-16)
Novel bidentate phosphine ligands BABIPhos featuring a biaryl bis-dihydrobenzooxaphosphole core are presented. Their synthesis was achieved via Pd-catalyzed reductive homocoupling of dihydrobenzooxaphosphole aryl triflates. An efficient route toward various analogues was also established, giving access to phosphines with different electronic
Olga V Zatolochnaya et al.
Chemical science, 9(19), 4505-4510 (2018-06-14)
A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution, simultaneously creating two contiguous stereogenic centers with
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