903973
Thianthrene S-oxide
≥95%
Sinonimo/i:
Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
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About This Item
Saggio
≥95%
Forma fisica
powder
Temperatura di conservazione
2-8°C
InChI
1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H
NYVGTLXTOJKHJN-UHFFFAOYSA-N
Applicazioni
Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.
Altre note
Site-selective and versatile aromatic C-H functionalization by thianthrenation
Video: Site-selective C-H functionalization by thianthrenation
In the Pipeline: New Chemistry, Making New Things
Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide
Video: Site-selective C-H functionalization by thianthrenation
In the Pipeline: New Chemistry, Making New Things
Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide
Note legali
Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Certificati d'analisi (COA)
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