901742

Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride

≥95%

• Sinonimo/i: (^PyrN^MeNN)Ni-Cl, (SP-4-4)-Chloro[N₁,N₁-dimethyl-N₂-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN₁,κN₂]nickel, Second-generation Nickamine
• Formula empirica (notazione di Hill): C₁₈H₂₂ClN₃Ni
• Peso molecolare: 374.53
• Codice UNSPSC: 12352101

Proprietà

• Saggio: ≥95%
• Forma fisica: powder or crystals
• Impiego in reazioni chimiche: core: nickel; reagent type: catalyst
• Stringa SMILE: CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl

Descrizione

Applicazioni

As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.

Altre note

From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 13 - Non Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable