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Sigma-Aldrich

Tris[2-(dimethylamino)ethyl]amine

97%

Sinonimo/i:

Me6TREN

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About This Item

Formula empirica (notazione di Hill):
C12H30N4
Numero CAS:
33527-91-2
Peso molecolare:
230.39
Numero MDL:
MFCD00015607
Codice UNSPSC:
12162002
ID PubChem:
329763980
NACRES:
NA.23

Livello qualitativo

100

Saggio

97%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.455

Densità

0.862 g/mL at 25 °C

Stringa SMILE

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3
VMGSQCIDWAUGLQ-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Tris[2-(dimethylamino)ethyl]amine (Me6TREN) is an aliphatic tertiary amine that forms a quadridentate ligand. It is majorly used in atom transfer radical polymerization (ATRP). It is a hexamethyl derivative of (2-aminoethyl)amine, also known as trenMe. It can be prepared by a modification of Ristempart′s synthesis.

Applicazioni

Atom Transfer Radical Polymerization (ATRP) ligand for the creation of telechelic polymers.
Me6TREN forms a complex with copper compounds which can potentially be used as ligands in metalloenzyme redox reactions.

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H314

Classi di pericolo

Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible, corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

219.9 °F - closed cup

Punto d’infiammabilità (°C)

104.4 °C - closed cup

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Xia Song et al.
Biomacromolecules, 17(12), 3957-3963 (2016-10-25)
Paclitaxel (PTX), a hydrophobic anticancer drug, is facing several clinical limitations such as low bioavailability and drug resistance. To solve the problems, a well-defined β-cyclodextrin-poly(N-isopropylacrylamide) star polymer was synthesized and used as a nanocarrier to improve the water solubility and
Expanding the scope of the photoinduced living radical polymerization of acrylates in the presence of CuBr2 and Me6-Tren
Anastasaki A, et al.
Macromolecules, 47(12), 3852-3859 (2014)
Tsarevsky, N. V.; Braunecker, W. A.; Brooks, S. J.; Matyjaszewski, K.
Marcromolecules, 39, 6817-6817 (2006)
Reversible Binding of Dioxygen by a Copper (I) Complex with Tris (2-dimethylaminoethyl) amine (Me6tren) as a Ligand
Becker M, et al.
Chemistry?A European Journal, 5(11), 3124-3129 (1999)
Nobuyuki Higashi et al.
Materials (Basel, Switzerland), 11(3) (2018-03-16)
Novel thermo-responsive ABA-type triblock copolymers (poly(NAAMe n
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