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Sigma-Aldrich

Copper(I) bromide

99.999% trace metals basis

Sinonimo/i:

Cuprous bromide

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About This Item

Formula condensata:
CuBr
Numero CAS:
Peso molecolare:
143.45
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.23

Saggio

99.999% trace metals basis

Forma fisica

powder

Impiego in reazioni chimiche

reagent type: catalyst
core: copper

Impurezze

≤15.0 ppm Trace Metal Analysis

Punto di fusione

504 °C (lit.)

Densità

4.71 g/mL at 25 °C (lit.)

applicazioni

battery manufacturing

Stringa SMILE

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1
NKNDPYCGAZPOFS-UHFFFAOYSA-M

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Descrizione generale

Copper(I) bromide is a faint green inorganic diamagnetic solid that has a polymeric structure like zinc sulfide. It is insoluble in water and widely used in the field of catalysis, nanomaterial synthesis, and solar cells.

Applicazioni

Copper(I) bromide can be used:
  • As a solution-processable hole transport layer (HTL) for organic solar cells (OSCs). CuBr enhances the power conversion efficiency of solar cells.
  • As a precursor to synthesize photoluminescent metal organic frameworks(MOFs).
  • To synthesize highly emissive three-coordinate copper(I) complexes as a dopant in OLEDs with maximum external quantum efficiency of 21.3%.
  • As a catalyst with ligands for atom transfer radical polymerization (ATRP) reaction of tertiary alkyl halides in 14 different solvents to determine the rate constant.
  • To synthesize macrocyclic polymer via intramolecular radical trap-assisted atom transfer radical coupling.

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)


Certificati d'analisi (COA)

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Articoli

Reagents for C–C Bond Formation

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Tools for Performing ATRP

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Vedi tutto

Protocolli

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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