467979
1,3-Dithiolane
97%
Sinonimo/i:
1,3-Dithiacyclopentane
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About This Item
Prodotti consigliati
Livello qualitativo
Saggio
97%
Indice di rifrazione
n20/D 1.599 (lit.)
P. eboll.
183 °C (lit.)
Densità
1.235 g/mL at 25 °C (lit.)
Stringa SMILE
C1CSCS1
InChI
1S/C3H6S2/c1-2-5-3-4-1/h1-3H2
IMLSAISZLJGWPP-UHFFFAOYSA-N
Categorie correlate
Descrizione generale
1,3-Dithiolane ,a sulfur containing heterocyclic building block, is a cyclic thioether. Fragmentation modes of 1,3-oxathiolane under electron-impact have been investigated.
Codice della classe di stoccaggio
10 - Combustible liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
154.4 °F - closed cup
Punto d’infiammabilità (°C)
68 °C - closed cup
Certificati d'analisi (COA)
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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.
Chemical communications (Cambridge, England), 46(31), 5778-5780 (2010-07-06)
A concise and diastereoselective formal total synthesis of triptolide, a natural product with a wide range of biological properties, is described. The key reaction is an unprecedented 6-endo-Trig cationic cyclization of a 2-alkenyl-1,3-dithiolane precursor induced by TMSOTf as Lewis acid.
Journal of combinatorial chemistry, 6(2), 181-195 (2004-03-09)
A synthetic strategy for the formation of resin-bound internal alpha-keto amide peptides suitable for protease inhibitor screening on solid support is presented. This general approach is based on the incorporation of alpha-keto amide building blocks during solid-phase peptide synthesis (SPPS).
Acta pharmacologica Sinica, 21(10), 897-904 (2001-08-15)
To investigate the effect of a group of novel synthetic dithiolane analogs of lignans and a well characterized platelet-activating factor (PAF) receptor antagonist, L659,989 on PAF-receptor binding, IFN-gamma- and lipopolysaccharide (LPS)-induced NO production, and steady-state inducible nitric-oxide synthase (iNOS) mRNA
Magnetic resonance in chemistry : MRC, 49(7), 443-449 (2011-05-07)
1-Oxo-1,3-dithiolane (4) and its cis- and trans-2-methyl (5,6), -4-methyl (7,8) and -5-methyl (9,10) derivatives were prepared by oxidizing the corresponding 1,3-dithiolanes (1-3) with NaIO(4) in water. The oxides were purified and their isomers separated using thin layer chromatography. The structural
Ionization and dissociation of cyclic ethers and thioethers by electron-impact. A comparison between 1, 3-dioxolane, 1, 3-dithiolane and 1, 3-oxathiolane.
Org. Mass Spectrom., 6(4), 415-423 (1972)
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