465348
2-Mercaptophenol
95%
Sinonimo/i:
2-Hydroxythiophenol
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About This Item
Prodotti consigliati
Saggio
95%
Indice di rifrazione
n20/D 1.6060 (lit.)
Densità
1.255 g/mL at 25 °C (lit.)
Stringa SMILE
Oc1ccccc1S
InChI
1S/C6H6OS/c7-5-3-1-2-4-6(5)8/h1-4,7-8H
VMKYTRPNOVFCGZ-UHFFFAOYSA-N
Descrizione generale
2-Mercaptophenol (H2mp) is a 1,2-bidentate sulfur containing ligand. It exhibits versatile coordination modes in its ligation to the transition metal atoms.
Applicazioni
2-Mercaptophenol may be employed as a complexing agent for the microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. It may be used for the synthesis of Vanadium (IV) complexes having mixed O, S donor ligands.
Avvertenze
Danger
Indicazioni di pericolo
Classi di pericolo
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Corr. 1B
Codice della classe di stoccaggio
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
230.0 °F - closed cup
Punto d’infiammabilità (°C)
110 °C - closed cup
Dispositivi di protezione individuale
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Inorganic chemistry, 35(2), 347-356 (1996-01-17)
Reaction of VO(acac)(2) with 2-mercaptophenol (mpH(2)) in the presence of triethylamine gives the mononuclear tris complex (Et(3)NH)(2)[V(mp)(3)] (1), in which the vanadyl oxygen has been displaced. An analogous reaction using 2-mercapto-4-methylphenol (mmpH(2)) afforded (Et(3)NH)(PNP)[V(mmp)(3)] (2), which was structurally characterized. 2
Analytica chimica acta, 615(2), 115-123 (2008-04-30)
A high-pressure microwave digestion was applied for microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. A mixture containing 3molL(-1) HCl, 50% aqueous methanol and 0.2molL(-1) citric acid (for masking co-extracted Fe(3+)) was selected as the most suitable
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Synthetic Communications, 29, 4459-4475 (1996)
Palladium complexes with simultaneous O: S coordination, syntheses, structures and characterization of complexes with 2-mercaptophenol or 2-mercaptopyridine N-oxide.
Polyhedron, 16(3), 369-375 (1997)
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