463558

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

• Sinonimo/i: Verkade superbase
• Formula empirica (notazione di Hill): C₉H₂₁N₄P
• Numero CAS: 120666-13-9
• Peso molecolare: 216.26
• Beilstein: 4970285
• Numero MDL: MFCD00269837
• Codice UNSPSC: 12352005
• ID PubChem: 24870079
• NACRES: NA.22

Proprietà

• Punto di fusione: 110-115 °C (lit.)
• Livello qualitativo: 100
• Stringa SMILE: CN1CCN2CCN(C)P1N(C)CC2
• InChI: 1S/C9H21N4P/c1-10-4-7-13-8-5-11(2)14(10)12(3)6-9-13/h4-9H2,1-3H3; PCYSWBQHCWWSFW-UHFFFAOYSA-N

Descrizione

Applicazioni

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane is involved as a reactant in:

• Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies.
• Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica.
• Protection / deprotection strategies for diazeniumdiolate chemistry.
• Encaging of the molecule to study the change in its catalytic ability.
• C-N coupling reactions.
• Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction.

Reactant involved in:

• Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies
• Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica
• Protection / deprotection strategies for diazeniumdiolate chemistry
• Encaging of the molecule to study change in its catalytic ability
• C-N coupling reactions
• Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)