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Documenti fondamentali

373761

Sigma-Aldrich

2,2,2-Trifluoroethyl methacrylate

contains 50-200 ppm MEHQ as inhibitor, 99%

Sinonimo/i:

2,2,2-Trifluoroethyl 2-methylprop-2-enoate

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About This Item

Formula condensata:
H2C=C(CH3)CO2CH2CF3
Numero CAS:
Peso molecolare:
168.11
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23

Livello qualitativo

Saggio

99%

Stato

liquid

contiene

50-200 ppm MEHQ as inhibitor

Indice di rifrazione

n20/D 1.361 (lit.)

P. ebollizione

59 °C/100 mmHg (lit.)

Densità

1.181 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

CC(=C)C(=O)OCC(F)(F)F

InChI

1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
QTKPMCIBUROOGY-UHFFFAOYSA-N

Descrizione generale

2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant.

Applicazioni

TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.

Pittogrammi

FlameSkull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

62.6 °F - closed cup

Punto d’infiammabilità (°C)

17 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Yoshinori Kadoma
Dental materials journal, 29(5), 602-608 (2010-09-10)
The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA) and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC) in order to improve the properties of fluorinated powder-liquid
Arda Yurtsever et al.
Electrophoresis, 30(4), 589-598 (2009-01-22)
A new, fluorinated monolithic stationary phase for CEC was first synthesized by a single-stage, thermally initiated copolymerization of a fluorinated monomer, 2,2,2-trifluoroethyl methacrylate (TFEM) and ethylene dimethacrylate (EDMA) in the presence of a porogen mixture. In this preparation, 2-acrylamido-2-methyl-1-propanesulfonic acid
Grafting modification of ramie fibers with poly (2, 2, 2-trifluoroethyl methacrylate) via reversible addition-fragmentation chain transfer (RAFT) polymerization in supercritical carbon dioxide
Liu X, et al.
Reactive and Functional Polymers, 70(12), 972-979 (2010)
Preparation and surface properties of poly (2, 2, 2-trifluoroethyl methacrylate) coatings modified with methyl acrylate
Xu A, et al.
Journal of Coatings Technology and Research, 13(5), 795-804 (2016)
Yoshinori Kadoma et al.
Dental materials journal, 28(5), 642-648 (2009-10-14)
In order to clarify the effect of fluorination of an adhesive resin on the durability of the resin bond to precious metal alloys, 2,2,2-trifluoroethyl methacrylate (TFEMA)-poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA)/TBBO adhesive resin was prepared. The tensile bond strength of this resin to

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