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367710

Sigma-Aldrich

Trichloroacetic anhydride

technical grade, 95%

Sinonimo/i:

(2,2,2-Trichloroacetyl) 2,2,2-trichloroacetate, Trichloroacetic acid anhydride

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About This Item

Formula condensata:
(Cl3CCO)2O
Numero CAS:
4124-31-6
Peso molecolare:
308.76
Beilstein:
980355
Numero CE:
223-925-3
Numero MDL:
MFCD00000793
Codice UNSPSC:
12352100
ID PubChem:
24862827
NACRES:
NA.22

Grado

technical grade

Livello qualitativo

100

Saggio

95%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.484 (lit.)

P. eboll.

139-141 °C/60 mmHg (lit.)

Densità

1.69 g/mL at 25 °C (lit.)

Stringa SMILE

ClC(Cl)(Cl)C(=O)OC(=O)C(Cl)(Cl)Cl

InChI

1S/C4Cl6O3/c5-3(6,7)1(11)13-2(12)4(8,9)10
MEFKFJOEVLUFAY-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Trichloroacetic anhydride is reported to be an efficient derivatization reagent, since it produces stable derivatives having both a higher mass fragmentation pattern and lesser volatility than derivatives of trifluoroacetic anhydride (TFAA) or heptafluorobutyric anhydride (HFBA). The interaction of thymidine 5′-phosphate with trichloroacetic anhydride in dimethylformamide and acetonitrile in the presence of tertiary amines hs been studied.

Applicazioni

Trichloroacetic anhydride may be used as derivatization reagent for the following studies:
  • Simultaneous analysis of amphetamine, methamphetamine and 3,4-methylenedioxymethamphetamine (MDMA or Ecstasy) in urine samples by solid-phase extraction, derivatization and gas chromatography/mass spectrometry.
  • Analysis of halogenated amphetamines in brain tissue from rats by gas chromatography with electron-capture detection (GC-ECD).
  • Quantitative determination of the metabolites of l-alpha-acetylmethadol (LAAM), such as noracetylmethadol, dinoracetylmethadol, methadol and normethadol by electron capture gas-liquid chromatography.

Pittogrammi

CorrosionExclamation mark
GHS05,GHS07

Avvertenze

Danger

Indicazioni di pericolo

H302 - H314

Classi di pericolo

Acute Tox. 4 Oral - Skin Corr. 1A

Codice della classe di stoccaggio

8A - Combustible, corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Trifluoroacetic acid, anhydride with trifluoromethanesulfonic acid technical grade, 90%

Sigma-Aldrich

308684

Trifluoroacetic acid, anhydride with trifluoromethanesulfonic acid

Hydrazobenzene

Sigma-Aldrich

126721

Hydrazobenzene

M L Owen et al.
Journal of pharmacological methods, 25(2), 147-155 (1991-04-01)
p-Chloro-alpha-fluoromethylphenylethylamine (fluoro-p-chloroamphetamine) (FpCA) has been shown in acute studies to be a less potent depletor of the neurotransmitter amine 5-hydroxytryptamine (5-HT) in brain than is p-chloroamphetamine (pCA). Gas chromatographic assay procedures for FpCA and PCA have been developed in our
R J Czarny et al.
Journal of analytical toxicology, 13(5), 257-262 (1989-09-01)
An analytical procedure for methamphetamine and amphetamine has been developed using 4-carbethoxyhexafluorobutyryl chloride. This derivatizing reagent has all the previously reported advantages of trichloroacetic anhydride (TCAA) in that it produces stable derivatives having both a higher mass fragmentation pattern and
B K Gan et al.
Journal of forensic sciences, 36(5), 1331-1341 (1991-09-01)
A rapid and effective solid-phase extraction procedure using Bond Elute Certify bonded silica sorbent cartridges was adopted to extract amphetamine, methamphetamine, and 3,4-methylenedioxymethamphetamine (MDMA or Ecstasy) from urine samples. The extract was derivatized with trichloroacetic anhydride prior to gas chromatography/mass
D H Lau et al.
Journal of chromatography, 129, 329-338 (1976-12-22)
Six reagents-trichloroacetyl chloride, trichloroacetic anhydride, pentafluorobenzoyl chloride, heptafluorobutyryl chloride, heptafluorobutyric anhydride, and trifluoroacetic anhydride- were evaluated as potential derivatizing reagents for quantitating the metabolites of l-alpha-acetylmethadol (LAAM) -noracetylmethadol, dinoracetylmethadol, methadol, and normethadol-by electron capture gas-liquid chromatography. All of the reagents
V S Bogachev et al.
Bioorganicheskaia khimiia, 29(1), 64-74 (2003-03-28)
The interaction of thymidine 5'-phosphate with trichloroacetic anhydride, trichloroacetyl chloride, and tribromoacetyl bromide was studied in dimethylformamide and acetonitrile in the presence of tertiary amines. The first two reactions gave the mixed anhydride of trichloroacetic and thymidylic acids (acyl phosphate)
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