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Key Documents

32851

Sigma-Aldrich

trans-1,4-Diaminocyclohexane

≥98.0% (GC)

Sinonimo/i:

trans-1,4-Cyclohexanediamine

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About This Item

Formula condensata:
C6H10(NH2)2
Numero CAS:
Peso molecolare:
114.19
Beilstein:
2801657
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Tensione di vapore

18 mmHg ( 87.2 °C)

Saggio

≥98.0% (GC)

Temp. autoaccensione

680 °F

Limite di esplosione

6 %

P. eboll.

197 °C (lit.)

Punto di fusione

68-72 °C (lit.)

Stringa SMILE

N[C@H]1CC[C@H](N)CC1

InChI

1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-
VKIRRGRTJUUZHS-IZLXSQMJSA-N

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Applicazioni

trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.

Pittogrammi

CorrosionExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

159.8 °F - closed cup

Punto d’infiammabilità (°C)

71 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificati d'analisi (COA)

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Hwan-Chul Yu et al.
Journal of nanoscience and nanotechnology, 11(7), 6141-6147 (2011-11-30)
Fully aliphatic polyimides (APIs) were prepared from rel-(1'R,3S5'S)-spiro[furan-3(2H),6'-[3]oxabicyclo[3.2.1]octane]-2,2',4',5(4H)-tetrone (DAn) as unsymmetrical spiro dianhydride, and either cis-trans-1,4-diaminocyclohexane (mix-DACH) or trans-1,4-diaminocyclohexane (trans-DACH) as diamine. Structure of all prepared monomers and polymers was confirmed via 1H-NMR and FT-IR. The solubility, optical transparency, and
Jana Kasparkova et al.
Biochemical pharmacology, 79(4), 552-564 (2009-09-29)
Earlier studies have described promising antitumor activity of a large-ring chelate complex [PtCl(2)(cis-1,4-DACH)] (DACH=diaminocyclohexane). Encouraging antitumor activity of this analogue of cisplatin prompted us to perform studies focused on the mechanistic basis of pharmacological effects of this complex. Four early
J D Hoeschele et al.
Journal of medicinal chemistry, 37(17), 2630-2636 (1994-08-19)
The first two analogs 5a,b of a new class of neutral large-ring square-planar Pt(II) chelate complexes of the generic structure [Pt(cis-1,4-dach)X2] were synthesized via a refined technique, structurally characterized by NMR (1H, 13C, 195Pt), FAB mass spectrometry, and X-ray crystallography
Synthesis and structure of a new layered zinc phosphate [C 6 N 2 H 1 6] 3. 5 [Zn 1 4 (PO 4) 7 (HPO 4) 7] in the presence of trans-1, 4-diaminocyclohexane.
Xing Y, et al.
Inorganic Chemistry Communications, 7(4), 475-477 (2004)
F Vianello et al.
Protein expression and purification, 15(2), 196-201 (1999-03-02)
A novel, simple, and rapid procedure for the purification of pea seedling amine oxidase is reported. The crude enzyme, obtained by ammonium sulfate fractionation, was purified in two steps: the first one by anion-exchange chromatography and the second one by

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