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Natriumhypochlorit -Lösung
reagent grade, available chlorine 4.00-4.99 %
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About This Item
Lineare Formel:
NaClO
CAS-Nummer:
Molekulargewicht:
74.44
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.21
Empfohlene Produkte
Qualität
reagent grade
Agentur
suitable for SM 4500 - NH3
Dampfdruck
17.5 mmHg ( 20 °C)
Form
liquid
Zusammensetzung
available chlorine, 4.00-4.99%
Eignung der Reaktion
reagent type: oxidant
Konzentration
4.00-4.99% (chlorine by Na2S2O3, titration)
Dichte
1.097 g/mL at 25 °C
Lagertemp.
2-8°C
SMILES String
[Na+].[O-]Cl
InChI
1S/ClO.Na/c1-2;/q-1;+1
InChIKey
SUKJFIGYRHOWBL-UHFFFAOYSA-N
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Allgemeine Beschreibung
Sodium hypochlorite (NaOCl) is a commonly used reagent in organic synthesis for many oxidation and chlorination reactions.
Anwendung
Sodium hypochlorite solution can be used as an oxidizing agent for the oxidation of:
It can also be used as a reagent in the:
- Primary alcohols to aldehydes or carboxylic acids and secondary alcohols to ketones.
- Aryl aldehydes to the corresponding acids in the presence of a phase-transfer catalyst.
- Ethers to esters by careful pH control (pH range of 8–9.5),
It can also be used as a reagent in the:
- Epoxidation of enones and polycyclic arenes.
- Oxidative degradation reaction
- N-Chlorination of primary and secondary amines
- Enantioselective epoxidation of α, β-unsaturated ketones
- Asymmetric dihydroxylation of olefins in the presence of an osmium catalyst
- Chlorination of allylic carbons in the presence of CeCl3
Leistungsmerkmale und Vorteile
- Readily available reagent
- Easily handled oxidizing agent
- No phase-transfer catalyst is necessary for the oxidation of substrates in the pH range 10–11
- Simplified waste disposal and lower toxicity
Haftungsausschluss
“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.”
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2
Lagerklassenschlüssel
12 - Non Combustible Liquids
WGK
WGK 2
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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