728551

Bis[(2-dimethylamino)phenyl]amin-Nickel(II)chlorid

≥97% (AT)

• Synonym(e): Chloro-[N²-[2-(dimethylamino-κN)phenyl]-N¹,N¹-dimethyl-1,2-benzenediaminato-κN¹,κN²]-nickel
• Empirische Formel (Hill-System): C₁₆H₂₀ClN₃Ni
• CAS-Nummer: 1033772-47-2
• Molekulargewicht: 348.50
• MDL-Nummer: MFCD17015253
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329764408
• NACRES: NA.22

Eigenschaften

• Assay: ≥97% (AT)
• Form: lumps
• Eignung der Reaktion: core: nickel; reagent type: catalyst
• SMILES String: CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
• InChI: 1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
• InChIKey: IRLHVNUEEKJBEL-UHFFFAOYSA-M

Beschreibung

Anwendung

Catalyst for:

• Alkyl-alkyl Kumada coupling of secondary alkyl halides
• Direct alkylation of heterocyclic C-H bonds
• Sonogashira coupling of nonactivated alkyl halides
• Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable