335363

[1,3-Bis(diphenylphosphin)propan]dichlornickel(II)

• Synonym(e): (1,3-dppp)NiCl₂, Ni(dppp)Cl₂
• Lineare Formel: [(C₆H₅)₂P(CH₂)₃P(C₆H₅)₂]NiCl₂
• CAS-Nummer: 15629-92-2
• Molekulargewicht: 542.04
• MDL-Nummer: MFCD00015318
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24860309
• NACRES: NA.22

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Eignung der Reaktion: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp (Schmelzpunkt): 213 °C (dec.) (lit.)
• SMILES String: Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
• InChI: 1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
• InChIKey: ZBQUMMFUJLOTQC-UHFFFAOYSA-L

Beschreibung

Anwendung

Catalyst for:

• Synthesis of block-copolythiophenes
• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
• Transfer condensation polymerization of conjugated polymers

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H315,H317,H319,H334,H335,H350
• P-Sätze: P202 - P261 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges