213403

N-Selectrid^® -Lösung

1.0 M in THF

• Synonym(e): Natrium-tri-sec.-butylborhydrid -Lösung
• Lineare Formel: NaB[CH(CH₃)C₂H₅]₃H
• CAS-Nummer: 67276-04-4
• Molekulargewicht: 206.15
• MDL-Nummer: MFCD00011709
• UNSPSC-Code: 12352001
• PubChem Substanz-ID: 24852780
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Eignung der Reaktion: reagent type: reductant
• Konzentration: 1.0 M in THF
• Dichte: 0.893 g/mL at 25 °C (lit.)
• SMILES String: [Na+].CCC(C)[BH-](C(C)CC)C(C)CC
• InChI: 1S/C12H28B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
• InChIKey: JUFGMKFPFVIKOY-UHFFFAOYSA-N

Beschreibung

Anwendung

• Reducing agent

Reactant for:

• Conjugate hydride reduction-initiated tandem cyclization reactions
• Sereoselective nucleophilic addition reactions

Rechtliche Hinweise

Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H302,H314,H335,H351
• P-Sätze: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 5.0 °F - closed cup
• Flammpunkt (°C): -15 °C - closed cup