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Supelco

Genistin

analytical standard

Sinônimo(s):

4′,5,7-Trihydroxyisoflavone 7-glucoside, Genistein 7-glucoside, Genistein-7-O-β-D-glucopyranoside, Genistoside, NSC 5112

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About This Item

Fórmula empírica (Notação de Hill):
C21H20O10
Número CAS:
Peso molecular:
432.38
Beilstein:
64479
Número MDL:
Código UNSPSC:
85151701
ID de substância PubChem:
NACRES:
NA.24

grau

analytical standard

Nível de qualidade

Ensaio

≥98.0% (HPLC)

prazo de validade

limited shelf life, expiry date on the label

técnica(s)

HPLC: suitable
gas chromatography (GC): suitable

aplicação(ões)

food and beverages

formato

neat

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

OC[C@H]1O[C@@H](Oc2cc(O)c3C(=O)C(=COc3c2)c4ccc(O)cc4)[C@H](O)[C@@H](O)[C@@H]1O

InChI

1S/C21H20O10/c22-7-15-18(26)19(27)20(28)21(31-15)30-11-5-13(24)16-14(6-11)29-8-12(17(16)25)9-1-3-10(23)4-2-9/h1-6,8,15,18-24,26-28H,7H2/t15-,18-,19+,20-,21-/m1/s1

chave InChI

ZCOLJUOHXJRHDI-CMWLGVBASA-N

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Descrição geral

Genistin belongs to the class of isoflavone glycosides generally extracted from soybeans.

Aplicação

Genistin has been used as an analytical reference standard for the analysis of genistin in:
  • Legumes by ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS) with electrospray ionization (ESI) source and multiple reaction monitoring (MRM) detection.

It may be used as an analytical reference standard for the determination of genistin in:
  • Soy-based foods and dietary supplements by LC coupled to absorbance detection and isotope-dilution mass spectrometry (IDMS), equipped with ESI source and selected ion monitoring (SIM) mode.
  • Soy products by colloidal gold-based indirect competitive immunochromatographic assay (ICA).
  • Rainbow trout muscle by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and LC-ESI-MS/MS.
  • Soybean flour by matrix solid phase dispersion extraction (MSPD) and LC with ultraviolet-diode array detection (UV-DAD).
  • Soymilk samples by HPLC-UV operating under the gradient elution mode.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Ações bioquímicas/fisiológicas

Selective inhibitor of mammalian terminal deoxynucleotidyl transferase (TdT), with no measurable effect on mammalian or microbial DNA polymerases.

Embalagem

Bottomless glass bottle. Contents are inside inserted fused cone.

Outras notas

This compound is commonly found in plants of the genus: glycyrrhiza

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Certificados de análise (COA)

Lot/Batch Number

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Genistein synthetic, ≥98% (HPLC), powder

Sigma-Aldrich

G6649

Genistein

Genistein primary reference standard

05360590

Genistein

Daidzein Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1858

Daidzein

Colloidal gold-based indirect competitive immunochromatographic assay for rapid detection of bioactive isoflavone glycosides daidzin and genistin in soy products.
Sakamoto S, et al.
Food Chemistry, 194, 191-195 (2016)
Liquid chromatography with absorbance detection and with isotope-dilution mass spectrometry for determination of isoflavones in soy standard reference materials.
Phillips MM, et al.
Analytical and Bioanalytical Chemistry, 409(4), 949-960 (2017)
Isoflavones quantification in rainbow trout muscle by QuEChERS tecnique and liquid chromatography coupled with mass spectrometry.
Merlanti R, et al.
J. Food Compos. Anal., 70(4), 114-124 (2018)
Determination of Isoflavones in Soybean Flour by Matrix Solid-Phase Dispersion Extraction and Liquid Chromatography with UV-Diode Array Detection.
Aresta A, et al.
Journal of Food Quality, 2017(4), 114-124 (2017)
Analysis of water-soluble bioactive compounds in commonly consumed soymilk in China.
Li YR, et al.
J. Food Compos. Anal., 46(4), 29-35 (2016)

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