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Sigma-Aldrich

Molybdenumhexacarbonyl

technical

Sinônimo(s):

Hexacarbonylmolybdenum(0)

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About This Item

Fórmula linear:
Mo(CO)6
Número CAS:
Peso molecular:
264.00
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

densidade de vapor

9.1 (vs air)

Nível de qualidade

grau

technical

Formulário

solid

adequação da reação

core: molybdenum
reagent type: catalyst

p.e.

156 °C (lit.)

pf

150 °C (dec.) (lit.)

densidade

1.96 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

chave InChI

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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Descrição geral

Molybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.

Aplicação

Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.

Pictogramas

Skull and crossbones

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Inhalation

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Microstructural analysis and Transport Properties of MoO and MoC nanostructures prepared by focused electron beam-induced deposition
Makise K, et al
Scientific Reports, 4 (2014)
An investigation of the chemistry of molybdenum hexacarbonyl on thin dehydroxylated alumina films in ultrahigh vacuum
Catalysis Letters, 91(1-2), 83-88 (2003)
In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
Nils-Fredrik K Kaiser et al.
Journal of combinatorial chemistry, 4(2), 109-111 (2002-03-12)
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in

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