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Documentos Principais

650609

Sigma-Aldrich

Metanol

≥99.9%, HPLC Plus, suitable for HPLC, poly-coated bottles

Sinônimo(s):

Álcool metílico

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About This Item

Fórmula linear:
CH3OH
Número CAS:
Peso molecular:
32.04
Beilstein:
1098229
Número CE:
Número MDL:
Código UNSPSC:
12190000
ID de substância PubChem:
NACRES:
NA.21

Nome do produto

Metanol, HPLC Plus, ≥99.9%, poly-coated bottles

grau

HPLC Plus

Nível de qualidade

densidade de vapor

1.11 (vs air)

pressão de vapor

410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

Ensaio

≥99.9%

Formulário

liquid

temperatura de autoignição

725 °F

Lim. expl.

36 %

técnica(s)

HPLC: suitable

Impurezas

≤0.0002 meq/g Titr. base
≤0.0003 meq/g Titr. acid
≤0.001% Carbonyl Compounds
≤1.0 ppb Fluorescence (quinine) at 254 nm
≤1.0 ppb Fluorescence (quinine) at 365 nm
<0.05% water

resíduo de evaporação

≤0.0001%

cor

APHA: ≤10

índice de refração

n20/D 1.329 (lit.)

p.e.

64.7 °C (lit.)

pf

−98 °C (lit.)

solubilidade

benzene: miscible(lit.)
ethanol: miscible(lit.)
water: miscible(lit.)

densidade

0.791 g/mL at 25 °C (lit.)
0.791 g/mL at 25 °C

Gradiente HPLC

≤2 mAU at 230 nm
≤5 mAU at 254 nm

λ

H2O reference

Absorção UV

λ: 205 nm Amax: 1.0
λ: 210 nm Amax: 0.80
λ: 220 nm Amax: 0.20
λ: 230 nm Amax: 0.10
λ: 250 nm Amax: 0.02
λ: 400 nm Amax: 0.005

Formato

neat

cadeia de caracteres SMILES

CO

InChI

1S/CH4O/c1-2/h2H,1H3

chave InChI

OKKJLVBELUTLKV-UHFFFAOYSA-N

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Descrição geral

Methanol (MeOH) is an organic solvent with a wide range of industrial applications. It is the main component of lithium batteries. It can be prepared by hydrogenation of CO2 under various conditions. MeOH is a toxic alcohol employed for denaturing ethyl alcohol. A study reports the preparation of biodiesel from canola oil using methanol under supercritical conditions.
Methanol is an alcohol. Its thermochemical conversion to C2-C10 hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.

Aplicação

Methanol (MeOH) may be used in the following studies:
  • Colony forming unit-fibroblast assay of bone marrow mononuclear cells.
  • As solvent for the preparation of extracts of hyphae of Aspergillus for the estimation of gliotoxin by reversed phase-HPLC.
  • Immunofluorescence studies.
  • To compose eluent for the ion-pair reverse-phase HPLC isolation of nucleotides and their decomposition products.
  • As eluent in the HPLC estimation of malondialdehyde in plasma, which is an indicator of oxidative stress.
Suitable for HPLC, spectrophotometry, and some LC-MS applications

Embalagem

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Nota de preparo

Product filtered through a 0.2 μm filter

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Órgãos-alvo

Eyes,Central nervous system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

49.5 °F - closed cup

Ponto de fulgor (°C)

9.7 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves


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Combining Low-Pressure CO2 Capture and Hydrogenation To Form Methanol.
Khusnutdinova JR, et al.
ACS Catalysis, 5(4), 2416-2422 (2015)
CO2 hydrogenation to methanol over CuZnGa catalysts prepared using microwave-assisted methods.
Cai W, et al.
Catalysis Today, 242, 193-199 (2015)
CO2 Hydrogenation to Methanol on Supported Au Catalysts under Moderate Reaction Conditions: Support and Particle Size Effects.
Hartadi Y, et al.
ChemSusChem, 8(3), 456-465 (2015)
Nomaan M Rezayee et al.
Journal of the American Chemical Society, 137(3), 1028-1031 (2015-01-17)
This Communication describes the hydrogenation of carbon dioxide to methanol via tandem catalysis with dimethylamine and a homogeneous ruthenium complex. Unlike previous examples with homogeneous catalysts, this CO2-to-CH3OH process proceeds under basic reaction conditions. The dimethylamine is proposed to play
Methanol.
R Von Burg
Journal of applied toxicology : JAT, 14(4), 309-313 (1994-07-01)

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