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Documentos Principais

372145

Sigma-Aldrich

Trichloroethylene

anhydrous, contains 40 ppm diisopropylamine as stabilizer, ≥99%

Sinônimo(s):

TCE, Trichloroethene

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About This Item

Fórmula linear:
ClCH=CCl2
Número CAS:
Peso molecular:
131.39
Beilstein:
1736782
Número CE:
Número MDL:
Código UNSPSC:
12352101
ID de substância PubChem:
NACRES:
NA.21

grau

anhydrous

Nível de qualidade

densidade de vapor

4.5 (vs air)

pressão de vapor

61 mmHg ( 20 °C)

Ensaio

≥99%

Formulário

liquid

temperatura de autoignição

770 °F

contém

40 ppm diisopropylamine as stabilizer

Impurezas

<0.002% water
<0.005% water (100 mL pkg)

resíduo de evaporação

<0.0005%

índice de refração

n20/D 1.476 (lit.)

p.e.

86.7 °C (lit.)

pf

−84.8 °C (lit.)

densidade

1.463 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

Cl\C=C(\Cl)Cl

InChI

1S/C2HCl3/c3-1-2(4)5/h1H

chave InChI

XSTXAVWGXDQKEL-UHFFFAOYSA-N

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Descrição geral

Trichloroethylene (TCE) is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. Without stabilizers, TCE is unstable and degrades easily in the presence of moisture air, light and heat, it can be minimized by adding diisopropylamine as a stabilizer. Various methods have been reported for its synthesis. One of them is by chlorinating ethylene dichloride. Since TCE is one of the most common industrial solvent it has led it to be a major contaminant found in the ground water. It has adverse effect on human health due to its potential toxicity and carcinogenicity. Its toxicity and carcinogenicity has been studied.
Many methods have been proposed for the mineralization of TCE.

Pictogramas

Health hazardExclamation mark

Palavra indicadora

Danger

Classificações de perigo

Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Órgãos-alvo

Central nervous system

Código de classe de armazenamento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

closed cup - does not flash

Ponto de fulgor (°C)

closed cup - does not flash

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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S Yamazaki et al.
Water research, 35(4), 1022-1028 (2001-03-10)
A recirculating system of aqueous trichloroethylene (TCE) solutions through the packed bed reactor with TiO2 pellets has been developed in order to mineralize TCE without difficulties for filtration and recovery of catalyst. The TiO2 pellets prepared by sol gel method
Anaerobic degradation of trichloroethylene in soil.
Kleopfer RD, et al.
Environmental Science & Technology, 19(3), 277-280 (1985)
E M Waters et al.
Journal of toxicology and environmental health, 2(3), 671-707 (1977-01-01)
Trichloroethylene (TCE) has been an industrial chemical of some importance for the past 50 years. First synthesized by Fischer in 1864, TCE has enjoyed considerable industrial usage as a degreaser and limited medical use as an inhalation anesthetic and analgesic.
Chlorinated Decreasing Solvents: Physical-Chemical Properties Affecting Aquifer Contamination and Remediation.
Jackson RE and Dwarakanath V.
Ground Water Monitoring & Remediation, 19(4), 102-110 (1999)
A L Teel et al.
Water research, 35(4), 977-984 (2001-03-10)
Contaminant degradation, stoichiometry, and role of hydroxyl radicals (OH*) in four Fenton's systems were investigated using trichloroethylene (TCE) as a model contaminant. A standard Fenton's system, a modified soluble iron system with a pulse input of hydrogen peroxide, and two

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