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M50834

Sigma-Aldrich

1-Methylimidazole

greener alternative

ReagentPlus®, 99%

Sinônimo(s):

N-Methylimidazole

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About This Item

Fórmula empírica (Notação de Hill):
C4H6N2
Número CAS:
616-47-7
Peso molecular:
82.10
Beilstein:
105197
Número CE:
210-484-7
Número MDL:
MFCD00005292
Código UNSPSC:
12352005
ID de substância PubChem:
24896975

fonte biológica

synthetic

Nível de qualidade

200

pressão de vapor

0.4 mmHg ( 20 °C)

linha de produto

ReagentPlus®

Ensaio

99%

forma

liquid

temperatura de autoignição

977 °F

Lim. expl.

15.7 %

características do produto alternativo mais ecológico

Catalysis
Learn more about the Principles of Green Chemistry.

índice de refração

n20/D 1.495 (lit.)

pb

198 °C (lit.)

pf

−6 °C (lit.)

solubilidade

water: soluble

densidade

1.03 g/mL at 25 °C (lit.)

categoria alternativa mais ecológica

Aligned,

cadeia de caracteres SMILES

Cn1ccnc1

InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

chave InChI

MCTWTZJPVLRJOU-UHFFFAOYSA-N

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Categorias relacionadas

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Aplicação

Co-catalyst for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

Informações legais

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

CorrosionSkull and crossbones
GHS05,GHS06

Palavra indicadora

Danger

Frases de perigo

H302 - H311 - H314

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

Código de classe de armazenamento

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

197.6 °F - closed cup

Ponto de fulgor (°C)

92 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Pengfei Zhang et al.
Journal of chromatography. A, 1218(22), 3459-3465 (2011-04-19)
The development of mixed-mode stationary phase to achieve multiple separation capabilities in one column is very important for high performance liquid chromatography. In this paper, a new specific stationary phase based on grafting N-methylimidazolium to a monolithic silica column was
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also
Wen-Xin Chen et al.
The Journal of organic chemistry, 77(20), 9236-9239 (2012-10-02)
We report herein that amides are excellent N-sources in the NHC-Pd(II)-Im complex 1 catalyzed amination of aryl chlorides. In the presence of KO(t)Bu, various aryl chlorides and amides can react smoothly to give the corresponding aminated products in moderate to
Ganesh N Pandian et al.
Bioorganic & medicinal chemistry, 20(8), 2656-2660 (2012-03-13)
Epigenetic modifications that govern the gene expression are often overlooked with the design of artificial genetic switches. N-Methylpyrrole-N-methylimidazole (PI) hairpin polyamides are programmable small DNA binding molecules that have been studied in the context of gene regulation. Recently, we synthesized
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