917060

1 M Biphenyl in DME

a precursor solution to prepare the prelithiation/presodiation reagent for disordered carbon, SiO, Sn, Sb, P, and S electrodes

• Fórmula empírica (Notação de Hill): C₁₂H₁₀
• Peso molecular: 154.21
• Número MDL: MFCD00003054
• Código UNSPSC: 12352401
• NACRES: NA.23

Propriedades

• Nível de qualidade: 100
• Formulário: liquid
• concentração: 1 M
• aplicação(ões): battery manufacturing
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: c2(ccccc2)c1ccccc1

Descrição

Aplicação

This product is biphenyl (Bp) solution in anhydrous DME (1 mol/L) is a precursor reagent that could be easily handled to prepare prelithiation or presodiation reagent. By direct reaction of Li metal, it forms a strong reducing reagent of Li-Bp. The resulting Li-Bp/DME reagent is applicable to prelithiate most of the active materials for Li ion batteries, such as Sn, Sb, P, S, SiO and other metal oxide. On the other hand, a presodiation reagent can be prepared by reacting Bp/DME solution with Na metal. Na-Bp/DME reagent can be used to presodiate hard carbon, a promising anode material in Na ion batteries.

Nota de preparo

Suggested Directions for use:

• Step 1 Preparation of Prelithiation/presodiation reagent

Before use of Li metal, scrub the lithium surface to remove oxide and nitride layers.
To prepare 1 M Li-Bp/DME reagent, > 0.07 g of Li metal is added into every 10 ml of 1 M BP/DME solution.
To prepare 1 M Na-Bp/DME reagent, > 0.23 g of Na metal is added into every 10 ml of 1 M BP/DME solution.

• Step 2 Prelithiation/presodiation of electrodes

For a 1 cm diameter electrode with 1-3 mg acitve material per cm², soak (10-60 min, times will vary with material) the electrode in ∼0.5-1 mL of prelithiation/presodiation reagent. Discard the solution and then wash the electrode twice with DME. Longer prelithiation/presodiation time may cause electrode structure deformation, leading to a decreased discharge/charge capacity.

Informações de segurança

• Pictogramas: GHS02,GHS08,GHS07,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H225,H315,H319,H332,H335,H360FD,H411
• Declarações de precaução: P210 - P273 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Classificações de perigo: Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): 33.8 °F
• Ponto de fulgor (°C): 1 °C