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Key Documents

805408

Sigma-Aldrich

FK 209 Co(III) PF6 salt

Sinônimo(s):

Greatcell Solar®, tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)cobalt(III) tri[hexafluorophosphate]

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About This Item

Fórmula empírica (Notação de Hill):
C36H45CoF18N9P3
Peso molecular:
1097.63
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Ensaio

98%

Nível de qualidade

forma

powder

cadeia de caracteres SMILES

CC(C)(C)C1=CC(N2N=CC=C2)=NC=C1.CC(C)(C)C3=CC=NC(N4C=CC=N4)=C3.CC(C)(C)C5=CC=NC(N6C=CC=N6)=C5.[Co+3]

InChI

1S/3C12H15N3.Co/c3*1-12(2,3)10-5-7-13-11(9-10)15-8-4-6-14-15;/h3*4-9H,1-3H3;/q;;;+3

chave InChI

GECNGXUHOILCGK-UHFFFAOYSA-N

Aplicação

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices.

Informações legais

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Declarações de precaução

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films

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