777692
(1,10-Phenanthroline)(trifluoromethyl)copper(I)
90%
Sinônimo(s):
Trifluoromethylator®
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About This Item
Fórmula empírica (Notação de Hill):
C13H8CuF3N2
Número CAS:
Peso molecular:
312.76
Número MDL:
Código UNSPSC:
12352101
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
90%
forma
solid
temperatura de armazenamento
2-8°C
InChI
1S/C12H8N2.CF3.Cu/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2-1(3)4;/h1-8H;;
chave InChI
CUQZQRIIFNWQSJ-UHFFFAOYSA-N
Descrição geral
(1,10-Phenanthroline)(trifluoromethyl)copper(I) [(Phen)Cu-CF3] can be prepared by treating [CuOt-Bu]4 with 1,10-phenanthroline, followed by the addition of (trifluoromethyl)trimethylsilane (CF3TMS). It is an easily handled, thermally stable, single-component reagent.
Aplicação
Trifluoromethylator, A New Arene Trifluoromethylation Reagent: (Phen)Cu-CF3
(Phen)Cu-CF3 can be used as a reagent for the trifluoromethylation of aryl iodides. Electron-rich and electron-deficient iodoarenes, as well as sterically-hindered iodoarenes, react in high yield under mild conditions. Electrophilic functional groups, including aldehydes, nitroarenes, ketones, and esters are tolerated. The substrate scope of this reagent is broad and the reagent has wide applicability for trifluoromethylation reactions.
It can also be used in the oxidative trifluoromethylation of organoboron reagents, and terminal alkynes through C-H activation.
(Phen)Cu-CF3 can be used as a reagent for the trifluoromethylation of aryl iodides. Electron-rich and electron-deficient iodoarenes, as well as sterically-hindered iodoarenes, react in high yield under mild conditions. Electrophilic functional groups, including aldehydes, nitroarenes, ketones, and esters are tolerated. The substrate scope of this reagent is broad and the reagent has wide applicability for trifluoromethylation reactions.
It can also be used in the oxidative trifluoromethylation of organoboron reagents, and terminal alkynes through C-H activation.
Informações legais
Trifluoromethylator is a registered trademark of Catylix, Inc
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
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A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.
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Angewandte Chemie (International ed. in English), 50(16), 3793-3798 (2011-03-29)
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