726192

Bis(4-methylphenyl)iodonium hexafluorophosphate

98%

• Sinônimo(s): Bis(p-tolyl)iodonium hexafluorophosphate
• Fórmula empírica (Notação de Hill): C₁₄H₁₄F₆IP
• Número CAS: 60565-88-0
• Peso molecular: 454.13
• Beilstein: 3581445
• Número CE: 262-301-5
• Número MDL: MFCD06656584
• Código UNSPSC: 12352300
• ID de substância PubChem: 329764214
• NACRES: NA.23

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥97.5% (TLC); 98%
• Formulário: solid
• cadeia de caracteres SMILES: F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1
• InChI: 1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1
• chave InChI: LHLVGWWCRPPKBC-UHFFFAOYSA-N

Descrição

Descrição geral

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Aplicação

• Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).


• Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).


• Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

Informações de segurança

• Pictogramas: GHS05
• Palavra indicadora: Danger
• Frases de perigo: H314
• Declarações de precaução: P280 - P305 + P351 + P338 - P310
• Classificações de perigo: Skin Corr. 1B
• Código de classe de armazenamento: 8A - Combustible corrosive hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable