679453

2-(Bromomethyl)phenylboronic acid

• Sinônimo(s): α-Bromo-o-tolueneboronic acid, o-Boronobenzyl bromide
• Fórmula empírica (Notação de Hill): C₇H₈BBrO₂
• Número CAS: 91983-14-1
• Peso molecular: 214.85
• Número MDL: MFCD01318941
• Código UNSPSC: 12352103
• ID de substância PubChem: 24885495
• NACRES: NA.22

Propriedades

• pf: 158-162 °C
• Nível de qualidade: 100
• grupo funcional: bromo
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: OB(O)c1ccccc1CBr
• InChI: 1S/C7H8BBrO2/c9-5-6-3-1-2-4-7(6)8(10)11/h1-4,10-11H,5H2
• chave InChI: MYVJCOQGXCONPE-UHFFFAOYSA-N

Descrição

Descrição geral

May contain varying amounts of anhydride.

Aplicação

2-(Bromomethyl)phenylboronic acid can be used as a reactant to synthesize:

• Boronic acid-functionalized benzyl viologen (o-BBV) from 4,4′-bipyridine. o-BBV finds its application as a chemosensor to sense glucose in aqueous water.
• 2-(azidomethyl)phenylboronic acid, which is further employed in the preparation of isoquinoline derivatives.
• Aryl boronic acid derivatives as fluorescent probe for hydrogen peroxide detection.

Reactant involved in:

• Studies of carbon-boron bond cleavage of phenylboronate-pendant cyclen
• Development of a sensory system to detect glucose or other monosaccharides and hydroxycarboxylates
• Synthesis of boronated triaryl and tetraaryl phosphonium salts used in cytotoxicity studies
• Colorimetry and fluorometry mercury determination with chemosensors composed of rhodamine and boronic acid groups
• Synthesis of imidazolium-containing boronic acids used as fluoride ion sensors
• Reactions with adenine for molecules with antiinflammatory antitumor activities 

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves