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Sigma-Aldrich

Molybdenum(V) chloride

anhydrous, powder, 99.99% trace metals basis (excluding W)

Sinônimo(s):

Molybdenum pentachloride, Molybdenum(5+) chloride

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About This Item

Fórmula linear:
MoCl5
Número CAS:
Peso molecular:
273.21
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

grau

anhydrous

Nível de qualidade

pressão de vapor

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

Ensaio

99.99% trace metals basis (excluding W)

Formulário

powder

Impurezas

≤150.0 ppm Trace Metal Analysis

p.e.

268 °C (lit.)

pf

194 °C (lit.)

densidade

2.928 g/mL at 25 °C (lit.)

aplicação(ões)

battery manufacturing

cadeia de caracteres SMILES

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

chave InChI

GICWIDZXWJGTCI-UHFFFAOYSA-I

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Descrição geral

Molybdenum(V) chloride, also called as molybdenum pentachloride is a Lewis acid with high oxidation potential. It is widely used as a catalyst in the field of organic synthesis and polymer chemistry. It is also used as a chemical vapor deposition precursor.

Aplicação

Molybdenum(V) chloride can be used:
  • As a catalyst for amidation of secondary benzyl alcohols.
  • As a precursor to fabricate MoS2 thin films by atomic layer deposition method.
  • As a primary catalyst for coordination polymerization of butadiene.
  • To fabricate superior anode materials for Na-ion and Li-ion batteries.
  • As a dual-function redox mediator for Li–O2 batteries to overcome thehigh polarization and low energy density issues.

Pictogramas

Corrosion

Palavra indicadora

Danger

Frases de perigo

Declarações de precaução

Classificações de perigo

Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Tin powder, -100 mesh, 99.99% trace metals basis

Sigma-Aldrich

755702

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Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular

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