449563

Borane diphenylphosphine complex

98%

• Sinônimo(s): (Diphenylphosphine)trihydroboron
• Fórmula linear: (C₆H₅)₂PH·BH₃
• Número CAS: 41593-58-2
• Peso molecular: 200.02
• Número MDL: MFCD00274254
• Código UNSPSC: 12352002
• ID de substância PubChem: 24868492
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: 98%
• Formulário: solid
• adequação da reação: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Reductions; reagent type: reductant
• p.e.: 148-150 °C/10 mmHg (lit.)
• pf: 47-50 °C (lit.)
• grupo funcional: phosphine
• cadeia de caracteres SMILES: B.[H]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
• chave InChI: XUFGOLYVDOBYLK-UHFFFAOYSA-N

Descrição

Aplicação

Reactant for:

• Nucleophilic addition reactions (anion)
• Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
• Deprotonation reactions
• Catalytic coupling with alkynyl bromides
• Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
• Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
• Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

Informações de segurança

• Pictogramas: GHS02
• Palavra indicadora: Danger
• Frases de perigo: H261
• Declarações de precaução: P231 + P232 - P422
• Classificações de perigo: Water-react 2
• Código de classe de armazenamento: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges